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{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I).

Xiao HQ, Zhang H - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The six-coordinate Na atom adopts a distorted octa-hedral coordination geometry.The O atoms of the perchlorate anion are disordered over two sites with site-occupancy factors of 0.697 (5) and 0.303 (5).O-H⋯O hydrogen bonding occurs.

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ABSTRACT
The mol-ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar with mean deviation of 5.2 (8)°. The coordination environment of the Cu(II) ion is distorted square-planar and it is N(2)O(2)-chelated by the 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Na atom is chelated by the four O atoms of the Schiff base ligand, and coordinated by a methanol mol-ecule and a perchlorate anion. The six-coordinate Na atom adopts a distorted octa-hedral coordination geometry. The O atoms of the perchlorate anion are disordered over two sites with site-occupancy factors of 0.697 (5) and 0.303 (5). O-H⋯O hydrogen bonding occurs.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme.
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Fap1: The molecular structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme.


{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I).

Xiao HQ, Zhang H - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969023&req=5

Fap1: The molecular structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme.
Bottom Line: The six-coordinate Na atom adopts a distorted octa-hedral coordination geometry.The O atoms of the perchlorate anion are disordered over two sites with site-occupancy factors of 0.697 (5) and 0.303 (5).O-H⋯O hydrogen bonding occurs.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The mol-ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar with mean deviation of 5.2 (8)°. The coordination environment of the Cu(II) ion is distorted square-planar and it is N(2)O(2)-chelated by the 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Na atom is chelated by the four O atoms of the Schiff base ligand, and coordinated by a methanol mol-ecule and a perchlorate anion. The six-coordinate Na atom adopts a distorted octa-hedral coordination geometry. The O atoms of the perchlorate anion are disordered over two sites with site-occupancy factors of 0.697 (5) and 0.303 (5). O-H⋯O hydrogen bonding occurs.

No MeSH data available.


Related in: MedlinePlus