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Bis(benzoyl-acetonato)bis-(1,3-di-4-pyridyl-propane)manganese(II).

Zhou Y, Zhao WN, Han L - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, [Mn(C(10)H(9)O(2))(2)(C(13)H(14)N(2))(2)], the Mn(II) ion lies on a crystallographic inversion center and has a slightly distorted octa-hedral coordination environment.Weak π-π stacking inter-actions, with centroid-centroid distances of 3.862 (2) and 3.887 (5) Å, and significant C-H⋯π inter-actions help to stabilize the crystal structure.The atoms of the unique terminal 4-pyridine-propane group are disordered over two sites, the ratio of refined occpancies being 0.712 (7):0.288 (7).

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ABSTRACT
In the title compound, [Mn(C(10)H(9)O(2))(2)(C(13)H(14)N(2))(2)], the Mn(II) ion lies on a crystallographic inversion center and has a slightly distorted octa-hedral coordination environment. Weak π-π stacking inter-actions, with centroid-centroid distances of 3.862 (2) and 3.887 (5) Å, and significant C-H⋯π inter-actions help to stabilize the crystal structure. The atoms of the unique terminal 4-pyridine-propane group are disordered over two sites, the ratio of refined occpancies being 0.712 (7):0.288 (7).

No MeSH data available.


Related in: MedlinePlus

Part of the crystal structure of (1), showing π···π stacking interactions and C—H···π interactions as dashed lines. The minor component disorder atoms have been removed for clarity.
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Fap2: Part of the crystal structure of (1), showing π···π stacking interactions and C—H···π interactions as dashed lines. The minor component disorder atoms have been removed for clarity.


Bis(benzoyl-acetonato)bis-(1,3-di-4-pyridyl-propane)manganese(II).

Zhou Y, Zhao WN, Han L - Acta Crystallogr Sect E Struct Rep Online (2009)

Part of the crystal structure of (1), showing π···π stacking interactions and C—H···π interactions as dashed lines. The minor component disorder atoms have been removed for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2969015&req=5

Fap2: Part of the crystal structure of (1), showing π···π stacking interactions and C—H···π interactions as dashed lines. The minor component disorder atoms have been removed for clarity.
Bottom Line: In the title compound, [Mn(C(10)H(9)O(2))(2)(C(13)H(14)N(2))(2)], the Mn(II) ion lies on a crystallographic inversion center and has a slightly distorted octa-hedral coordination environment.Weak π-π stacking inter-actions, with centroid-centroid distances of 3.862 (2) and 3.887 (5) Å, and significant C-H⋯π inter-actions help to stabilize the crystal structure.The atoms of the unique terminal 4-pyridine-propane group are disordered over two sites, the ratio of refined occpancies being 0.712 (7):0.288 (7).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Mn(C(10)H(9)O(2))(2)(C(13)H(14)N(2))(2)], the Mn(II) ion lies on a crystallographic inversion center and has a slightly distorted octa-hedral coordination environment. Weak π-π stacking inter-actions, with centroid-centroid distances of 3.862 (2) and 3.887 (5) Å, and significant C-H⋯π inter-actions help to stabilize the crystal structure. The atoms of the unique terminal 4-pyridine-propane group are disordered over two sites, the ratio of refined occpancies being 0.712 (7):0.288 (7).

No MeSH data available.


Related in: MedlinePlus