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(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-κN)trichloridocobalt(II).

Luachan S, Yotnoi B, Prior TJ, Rujiwatra A - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The title compound, [Co(C(10)H(21)N(2))Cl(3)], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template.The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups.These mol-ecules inter-act by way of C-H⋯Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array.

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ABSTRACT
The title compound, [Co(C(10)H(21)N(2))Cl(3)], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coordinated by three chloride anions and one 1-butyl-diaza-bicyclo-[2.2.2]octan-1-ium cation. The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups. These mol-ecules inter-act by way of C-H⋯Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array.

No MeSH data available.


Molecular packing in unit cell.
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Fap5: Molecular packing in unit cell.


(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-κN)trichloridocobalt(II).

Luachan S, Yotnoi B, Prior TJ, Rujiwatra A - Acta Crystallogr Sect E Struct Rep Online (2009)

Molecular packing in unit cell.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2968682&req=5

Fap5: Molecular packing in unit cell.
Bottom Line: The title compound, [Co(C(10)H(21)N(2))Cl(3)], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template.The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups.These mol-ecules inter-act by way of C-H⋯Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Co(C(10)H(21)N(2))Cl(3)], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coordinated by three chloride anions and one 1-butyl-diaza-bicyclo-[2.2.2]octan-1-ium cation. The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups. These mol-ecules inter-act by way of C-H⋯Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array.

No MeSH data available.