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Chlorido{2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).

Li MJ, Yan PF, Li GM, Li HF - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title complex, [Mn(C(17)H(16)N(2)O(2))Cl], the Mn(III) ion is coordinated by two O [Mn-O = 1.719 (2) and 1.813 (2) Å] and two N [Mn-N = 1.824 (2) and 1.931 (2) Å] atoms from the tetra-dentate Schiff base ligand and a chloride anion [Mn-Cl = 2.9634 (16) Å] in a square-pyramidal geometry.In the ligand, the two benzene rings form a dihedral angle of 68.06 (5)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

ABSTRACT
In the title complex, [Mn(C(17)H(16)N(2)O(2))Cl], the Mn(III) ion is coordinated by two O [Mn-O = 1.719 (2) and 1.813 (2) Å] and two N [Mn-N = 1.824 (2) and 1.931 (2) Å] atoms from the tetra-dentate Schiff base ligand and a chloride anion [Mn-Cl = 2.9634 (16) Å] in a square-pyramidal geometry. In the ligand, the two benzene rings form a dihedral angle of 68.06 (5)°.

No MeSH data available.


The molecular structure of (I), showing 30% probability displacement ellipsoids.
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Fap1: The molecular structure of (I), showing 30% probability displacement ellipsoids.


Chlorido{2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).

Li MJ, Yan PF, Li GM, Li HF - Acta Crystallogr Sect E Struct Rep Online (2009)

The molecular structure of (I), showing 30% probability displacement ellipsoids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2968646&req=5

Fap1: The molecular structure of (I), showing 30% probability displacement ellipsoids.
Bottom Line: In the title complex, [Mn(C(17)H(16)N(2)O(2))Cl], the Mn(III) ion is coordinated by two O [Mn-O = 1.719 (2) and 1.813 (2) Å] and two N [Mn-N = 1.824 (2) and 1.931 (2) Å] atoms from the tetra-dentate Schiff base ligand and a chloride anion [Mn-Cl = 2.9634 (16) Å] in a square-pyramidal geometry.In the ligand, the two benzene rings form a dihedral angle of 68.06 (5)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

ABSTRACT
In the title complex, [Mn(C(17)H(16)N(2)O(2))Cl], the Mn(III) ion is coordinated by two O [Mn-O = 1.719 (2) and 1.813 (2) Å] and two N [Mn-N = 1.824 (2) and 1.931 (2) Å] atoms from the tetra-dentate Schiff base ligand and a chloride anion [Mn-Cl = 2.9634 (16) Å] in a square-pyramidal geometry. In the ligand, the two benzene rings form a dihedral angle of 68.06 (5)°.

No MeSH data available.