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Poly[[[diisothio-cyanato-cobalt(II)]-bis-[μ-4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol]] dimethyl-formamide disolvate dihydrate].

Chu ZL - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol (L) ligands, and by two N atoms from two axial thio-cyanate anions [Co-N = 2.104 (3)-2.144 (3) Å].The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane.The dimethyl-formamide and solvent water mol-ecules participate in inter-molecular O-H⋯O and O-H⋯S hydrogen bonds, which consolidate the crystal packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of Molecular Engineering & Applied Chemistry, School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, People's Republic of China.

ABSTRACT
In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol (L) ligands, and by two N atoms from two axial thio-cyanate anions [Co-N = 2.104 (3)-2.144 (3) Å]. The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane. The dimethyl-formamide and solvent water mol-ecules participate in inter-molecular O-H⋯O and O-H⋯S hydrogen bonds, which consolidate the crystal packing.

No MeSH data available.


Related in: MedlinePlus

A portion of the crystal structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering [symmetry codes: (A) -x + 1, -y + 1, -z + 1; (B) -x + 1, y - 1/2, -z + 3/2; (C) x, -y + 3/2, z - 1/2].
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Fap1: A portion of the crystal structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering [symmetry codes: (A) -x + 1, -y + 1, -z + 1; (B) -x + 1, y - 1/2, -z + 3/2; (C) x, -y + 3/2, z - 1/2].


Poly[[[diisothio-cyanato-cobalt(II)]-bis-[μ-4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol]] dimethyl-formamide disolvate dihydrate].

Chu ZL - Acta Crystallogr Sect E Struct Rep Online (2009)

A portion of the crystal structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering [symmetry codes: (A) -x + 1, -y + 1, -z + 1; (B) -x + 1, y - 1/2, -z + 3/2; (C) x, -y + 3/2, z - 1/2].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2968591&req=5

Fap1: A portion of the crystal structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering [symmetry codes: (A) -x + 1, -y + 1, -z + 1; (B) -x + 1, y - 1/2, -z + 3/2; (C) x, -y + 3/2, z - 1/2].
Bottom Line: In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol (L) ligands, and by two N atoms from two axial thio-cyanate anions [Co-N = 2.104 (3)-2.144 (3) Å].The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane.The dimethyl-formamide and solvent water mol-ecules participate in inter-molecular O-H⋯O and O-H⋯S hydrogen bonds, which consolidate the crystal packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of Molecular Engineering & Applied Chemistry, School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, People's Republic of China.

ABSTRACT
In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol (L) ligands, and by two N atoms from two axial thio-cyanate anions [Co-N = 2.104 (3)-2.144 (3) Å]. The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane. The dimethyl-formamide and solvent water mol-ecules participate in inter-molecular O-H⋯O and O-H⋯S hydrogen bonds, which consolidate the crystal packing.

No MeSH data available.


Related in: MedlinePlus