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2-De-oxy-2,3-O-isopropyl-idene-2,4-di-C-methyl-β-l-arabinose.

Booth KV, Jenkinson SF, Fleet GW, Watkin DJ - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: The pyran-ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration.The absolute stereochemistry was determined from the starting material.The crystal structure consists of O-H⋯O hydrogen-bonded chains of mol-ecules running parallel to the b axis.

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ABSTRACT
X-ray crystallography unequivocally confirmed the stereochemistry of the C atom at position 2 in the carbon scaffold of the title mol-ecule, C(10)H(18)O(4). The pyran-ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration. The absolute stereochemistry was determined from the starting material. The crystal structure consists of O-H⋯O hydrogen-bonded chains of mol-ecules running parallel to the b axis.

No MeSH data available.


Synthetic Scheme
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Fap1: Synthetic Scheme


2-De-oxy-2,3-O-isopropyl-idene-2,4-di-C-methyl-β-l-arabinose.

Booth KV, Jenkinson SF, Fleet GW, Watkin DJ - Acta Crystallogr Sect E Struct Rep Online (2009)

Synthetic Scheme
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2968580&req=5

Fap1: Synthetic Scheme
Bottom Line: The pyran-ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration.The absolute stereochemistry was determined from the starting material.The crystal structure consists of O-H⋯O hydrogen-bonded chains of mol-ecules running parallel to the b axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
X-ray crystallography unequivocally confirmed the stereochemistry of the C atom at position 2 in the carbon scaffold of the title mol-ecule, C(10)H(18)O(4). The pyran-ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration. The absolute stereochemistry was determined from the starting material. The crystal structure consists of O-H⋯O hydrogen-bonded chains of mol-ecules running parallel to the b axis.

No MeSH data available.