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catena-Poly[[[triaqua-(nitrato-κO,O')neodymium(III)]-bis-(μ(2)-pyridinium-4-carboxyl-ato-κO:O')] bis-(perchlorate) monohydrate].

Pu JZ - Acta Crystallogr Sect E Struct Rep Online (2009)

Bottom Line: In the title compound, {[Nd(NO(3))(C(6)H(5)NO(2))(2)(H(2)O)(3)](ClO(4))(2)·H(2)O}(n), the Nd(III) atom is nine-coordinated by four O atoms from four pyridinium-4-carboxyl-ate ligands, two O atoms from a chelating nitrate anion and three water mol-ecules in a distorted tricapped trigonal-prismatic coordination geometry.Adjacent Nd atoms are linked by the bidentate pyridinium-4-carboxyl-ate ligands into a chain running along the b axis.The chains are further connected by O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Pharmacy, Zunyi Medical College, Zunyi, Guizhou 563003, People's Republic of China.

ABSTRACT
In the title compound, {[Nd(NO(3))(C(6)H(5)NO(2))(2)(H(2)O)(3)](ClO(4))(2)·H(2)O}(n), the Nd(III) atom is nine-coordinated by four O atoms from four pyridinium-4-carboxyl-ate ligands, two O atoms from a chelating nitrate anion and three water mol-ecules in a distorted tricapped trigonal-prismatic coordination geometry. Adjacent Nd atoms are linked by the bidentate pyridinium-4-carboxyl-ate ligands into a chain running along the b axis. The chains are further connected by O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network.

No MeSH data available.


A packing view of the title compound, showing hydrogen bonds (dashed lines).
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Fap3: A packing view of the title compound, showing hydrogen bonds (dashed lines).


catena-Poly[[[triaqua-(nitrato-κO,O')neodymium(III)]-bis-(μ(2)-pyridinium-4-carboxyl-ato-κO:O')] bis-(perchlorate) monohydrate].

Pu JZ - Acta Crystallogr Sect E Struct Rep Online (2009)

A packing view of the title compound, showing hydrogen bonds (dashed lines).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2968357&req=5

Fap3: A packing view of the title compound, showing hydrogen bonds (dashed lines).
Bottom Line: In the title compound, {[Nd(NO(3))(C(6)H(5)NO(2))(2)(H(2)O)(3)](ClO(4))(2)·H(2)O}(n), the Nd(III) atom is nine-coordinated by four O atoms from four pyridinium-4-carboxyl-ate ligands, two O atoms from a chelating nitrate anion and three water mol-ecules in a distorted tricapped trigonal-prismatic coordination geometry.Adjacent Nd atoms are linked by the bidentate pyridinium-4-carboxyl-ate ligands into a chain running along the b axis.The chains are further connected by O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Pharmacy, Zunyi Medical College, Zunyi, Guizhou 563003, People's Republic of China.

ABSTRACT
In the title compound, {[Nd(NO(3))(C(6)H(5)NO(2))(2)(H(2)O)(3)](ClO(4))(2)·H(2)O}(n), the Nd(III) atom is nine-coordinated by four O atoms from four pyridinium-4-carboxyl-ate ligands, two O atoms from a chelating nitrate anion and three water mol-ecules in a distorted tricapped trigonal-prismatic coordination geometry. Adjacent Nd atoms are linked by the bidentate pyridinium-4-carboxyl-ate ligands into a chain running along the b axis. The chains are further connected by O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network.

No MeSH data available.