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catena-Poly[[[N,N'-bis-(3-methoxy-benzyl-idene)ethyl-enediamine]copper(I)]-μ-thio-cyanato-κN:S].

Khalaji AD, Hadadzadeh H, Gotoh K, Ishida H - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the cyrstal structure of the title compound, [Cu(NCS)(C(18)H(20)N(2)O(2))](n), the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions.The thio-cyanate anion bridges the Cu(I) atoms, forming a zigzag chain along [101].The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

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ABSTRACT
In the cyrstal structure of the title compound, [Cu(NCS)(C(18)H(20)N(2)O(2))](n), the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the Cu(I) atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

No MeSH data available.


The molecular structure of the title compound with atom-labeling scheme. Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: The molecular structure of the title compound with atom-labeling scheme. Displacement ellipsoids are drawn at the 50% probability level.


catena-Poly[[[N,N'-bis-(3-methoxy-benzyl-idene)ethyl-enediamine]copper(I)]-μ-thio-cyanato-κN:S].

Khalaji AD, Hadadzadeh H, Gotoh K, Ishida H - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound with atom-labeling scheme. Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967908&req=5

Fap1: The molecular structure of the title compound with atom-labeling scheme. Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: In the cyrstal structure of the title compound, [Cu(NCS)(C(18)H(20)N(2)O(2))](n), the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions.The thio-cyanate anion bridges the Cu(I) atoms, forming a zigzag chain along [101].The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the cyrstal structure of the title compound, [Cu(NCS)(C(18)H(20)N(2)O(2))](n), the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the Cu(I) atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

No MeSH data available.