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(4-Hydr-oxy-2-oxidobenzaldehyde thio-semicarbazonato-κO,N,S)(1,10-phenanthroline-κN,N')zinc(II) dimethyl sulfoxide disolvate monohydrate.

Tan KW, Ng CH, Maah MJ, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment.Hydrogen bonds link the mononuclear mol-ecule, the water and the dimethyl sulfoxide (DMSO) mol-ecules into a linear chain motif.One DMSO mol-ecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio.

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ABSTRACT
The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear mol-ecule, the water and the dimethyl sulfoxide (DMSO) mol-ecules into a linear chain motif. One DMSO mol-ecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio.

No MeSH data available.


Thermal ellipsoid (Barbour, 2001) plot of Zn(C12H8N2)(C8H7N3O2S).2DMSO.H2O at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radii. The disorder in the DMSO is not shown.
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Fap1: Thermal ellipsoid (Barbour, 2001) plot of Zn(C12H8N2)(C8H7N3O2S).2DMSO.H2O at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radii. The disorder in the DMSO is not shown.


(4-Hydr-oxy-2-oxidobenzaldehyde thio-semicarbazonato-κO,N,S)(1,10-phenanthroline-κN,N')zinc(II) dimethyl sulfoxide disolvate monohydrate.

Tan KW, Ng CH, Maah MJ, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Thermal ellipsoid (Barbour, 2001) plot of Zn(C12H8N2)(C8H7N3O2S).2DMSO.H2O at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radii. The disorder in the DMSO is not shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967903&req=5

Fap1: Thermal ellipsoid (Barbour, 2001) plot of Zn(C12H8N2)(C8H7N3O2S).2DMSO.H2O at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radii. The disorder in the DMSO is not shown.
Bottom Line: The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment.Hydrogen bonds link the mononuclear mol-ecule, the water and the dimethyl sulfoxide (DMSO) mol-ecules into a linear chain motif.One DMSO mol-ecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear mol-ecule, the water and the dimethyl sulfoxide (DMSO) mol-ecules into a linear chain motif. One DMSO mol-ecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio.

No MeSH data available.