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Dichlorido(10,11,12,13-tetra-hydro-4,5,9,14-tetra-azabenzo[b]triphenyl-ene)cadmium(II) hemihydrate.

Li CX, Li XY, Liu CB, Yan YS, Che GB - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [CdCl(2)(C(18)H(14)N(4))(2)]·0.5H(2)O, the Cd atom assumes a distorted octa-hedral trans-CdCl(2)N(4) geometry arising from its coordination by two N,N'-bidentate 10,11,12,13-tetra-hydro-4,5,9,14-tetra-azabenzo[b]triphenyl-ene (TBBT) mol-ecules and two chloride ions.In the crystal, π-π aromatic stacking inter-actions between adjacent TTBT rings are seen, with a centroid-centroid distance of 3.604 (3) Å.An O-H⋯Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs.

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ABSTRACT
In the title compound, [CdCl(2)(C(18)H(14)N(4))(2)]·0.5H(2)O, the Cd atom assumes a distorted octa-hedral trans-CdCl(2)N(4) geometry arising from its coordination by two N,N'-bidentate 10,11,12,13-tetra-hydro-4,5,9,14-tetra-azabenzo[b]triphenyl-ene (TBBT) mol-ecules and two chloride ions. In the crystal, π-π aromatic stacking inter-actions between adjacent TTBT rings are seen, with a centroid-centroid distance of 3.604 (3) Å. An O-H⋯Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs.

No MeSH data available.


A view of the crystal packing, showing the π-π stacking and intermolecular hydrogen bonds interaction. H atoms have been omitted. [Symmetry codes: (A) x, -y + 5/2, z - 1/2; (B) x, y, z + 1; (C) x, -y + 5/2, z - 3/2; (AA) x, -y + 5/2, z - 3/2; (D) -x + 1, -y + 1, -z; (E) -x + 1, y + 3/2, -z + 1/2; (F) -x + 1, -y + 1, -z + 1; (G) -x + 1, y + 3/2, -z + 3/2]
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Fap2: A view of the crystal packing, showing the π-π stacking and intermolecular hydrogen bonds interaction. H atoms have been omitted. [Symmetry codes: (A) x, -y + 5/2, z - 1/2; (B) x, y, z + 1; (C) x, -y + 5/2, z - 3/2; (AA) x, -y + 5/2, z - 3/2; (D) -x + 1, -y + 1, -z; (E) -x + 1, y + 3/2, -z + 1/2; (F) -x + 1, -y + 1, -z + 1; (G) -x + 1, y + 3/2, -z + 3/2]


Dichlorido(10,11,12,13-tetra-hydro-4,5,9,14-tetra-azabenzo[b]triphenyl-ene)cadmium(II) hemihydrate.

Li CX, Li XY, Liu CB, Yan YS, Che GB - Acta Crystallogr Sect E Struct Rep Online (2008)

A view of the crystal packing, showing the π-π stacking and intermolecular hydrogen bonds interaction. H atoms have been omitted. [Symmetry codes: (A) x, -y + 5/2, z - 1/2; (B) x, y, z + 1; (C) x, -y + 5/2, z - 3/2; (AA) x, -y + 5/2, z - 3/2; (D) -x + 1, -y + 1, -z; (E) -x + 1, y + 3/2, -z + 1/2; (F) -x + 1, -y + 1, -z + 1; (G) -x + 1, y + 3/2, -z + 3/2]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967896&req=5

Fap2: A view of the crystal packing, showing the π-π stacking and intermolecular hydrogen bonds interaction. H atoms have been omitted. [Symmetry codes: (A) x, -y + 5/2, z - 1/2; (B) x, y, z + 1; (C) x, -y + 5/2, z - 3/2; (AA) x, -y + 5/2, z - 3/2; (D) -x + 1, -y + 1, -z; (E) -x + 1, y + 3/2, -z + 1/2; (F) -x + 1, -y + 1, -z + 1; (G) -x + 1, y + 3/2, -z + 3/2]
Bottom Line: In the title compound, [CdCl(2)(C(18)H(14)N(4))(2)]·0.5H(2)O, the Cd atom assumes a distorted octa-hedral trans-CdCl(2)N(4) geometry arising from its coordination by two N,N'-bidentate 10,11,12,13-tetra-hydro-4,5,9,14-tetra-azabenzo[b]triphenyl-ene (TBBT) mol-ecules and two chloride ions.In the crystal, π-π aromatic stacking inter-actions between adjacent TTBT rings are seen, with a centroid-centroid distance of 3.604 (3) Å.An O-H⋯Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [CdCl(2)(C(18)H(14)N(4))(2)]·0.5H(2)O, the Cd atom assumes a distorted octa-hedral trans-CdCl(2)N(4) geometry arising from its coordination by two N,N'-bidentate 10,11,12,13-tetra-hydro-4,5,9,14-tetra-azabenzo[b]triphenyl-ene (TBBT) mol-ecules and two chloride ions. In the crystal, π-π aromatic stacking inter-actions between adjacent TTBT rings are seen, with a centroid-centroid distance of 3.604 (3) Å. An O-H⋯Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs.

No MeSH data available.