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Aquabis-(6-bromo-picolinato-κN,O)copper(II).

Hu FL, Yue Z, Yan M, Luo WQ, Yin XH - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol-ecule, with one N atom in an axial site and the other in an equatorial site.The dihedral angle between the pyridine ring planes is 67.6 (2)°.In the crystal, O-H⋯O hydrogen bonds result in chains propagating in [100].

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Affiliation: College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, People's Republic of China.

ABSTRACT
In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol-ecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring planes is 67.6 (2)°. In the crystal, O-H⋯O hydrogen bonds result in chains propagating in [100].

No MeSH data available.


Part of the hydrogen bonding network, the hydrogen bonded interactions are showing as dashed lines. [symmetry codes: (I) -1+x, y, z; (II) 1-x, -y, 2-z; (III) 2-x, 1-y, 1-z; (IV) x, 1+y, -1+z; (V) 1-x, 1-y, 1-z.]
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Fap2: Part of the hydrogen bonding network, the hydrogen bonded interactions are showing as dashed lines. [symmetry codes: (I) -1+x, y, z; (II) 1-x, -y, 2-z; (III) 2-x, 1-y, 1-z; (IV) x, 1+y, -1+z; (V) 1-x, 1-y, 1-z.]


Aquabis-(6-bromo-picolinato-κN,O)copper(II).

Hu FL, Yue Z, Yan M, Luo WQ, Yin XH - Acta Crystallogr Sect E Struct Rep Online (2008)

Part of the hydrogen bonding network, the hydrogen bonded interactions are showing as dashed lines. [symmetry codes: (I) -1+x, y, z; (II) 1-x, -y, 2-z; (III) 2-x, 1-y, 1-z; (IV) x, 1+y, -1+z; (V) 1-x, 1-y, 1-z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967890&req=5

Fap2: Part of the hydrogen bonding network, the hydrogen bonded interactions are showing as dashed lines. [symmetry codes: (I) -1+x, y, z; (II) 1-x, -y, 2-z; (III) 2-x, 1-y, 1-z; (IV) x, 1+y, -1+z; (V) 1-x, 1-y, 1-z.]
Bottom Line: In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol-ecule, with one N atom in an axial site and the other in an equatorial site.The dihedral angle between the pyridine ring planes is 67.6 (2)°.In the crystal, O-H⋯O hydrogen bonds result in chains propagating in [100].

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, People's Republic of China.

ABSTRACT
In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol-ecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring planes is 67.6 (2)°. In the crystal, O-H⋯O hydrogen bonds result in chains propagating in [100].

No MeSH data available.