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Aqua-(imino-diacetato-κO,N,O')(1,10-phenanthroline-κN,N')cobalt(II) monohydrate.

Ng HL, Ng CH, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The imino-diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa-hedron around the metal atom.The metal atom is also chelated by the N-heterocycle.The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio.

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ABSTRACT
The imino-diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa-hedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water mol-ecules inter-act through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio.

No MeSH data available.


Related in: MedlinePlus

Thermal ellipsoid plot (Barbour, 2001) of Co(C12H8N2)(C4H5NO4)(H2O).H2O at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.
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Fap1: Thermal ellipsoid plot (Barbour, 2001) of Co(C12H8N2)(C4H5NO4)(H2O).H2O at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.


Aqua-(imino-diacetato-κO,N,O')(1,10-phenanthroline-κN,N')cobalt(II) monohydrate.

Ng HL, Ng CH, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Thermal ellipsoid plot (Barbour, 2001) of Co(C12H8N2)(C4H5NO4)(H2O).H2O at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967887&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of Co(C12H8N2)(C4H5NO4)(H2O).H2O at the 70% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: The imino-diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa-hedron around the metal atom.The metal atom is also chelated by the N-heterocycle.The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The imino-diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa-hedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water mol-ecules inter-act through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio.

No MeSH data available.


Related in: MedlinePlus