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Di-μ-chlorido-bis-[(2,2'-bibenzimidazole)chloridocadmium(II)].

Liu G - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title binuclear complex, [Cd(2)Cl(4)(C(14)H(10)N(4))(2)], was synthesized by the hydro-thermal reaction of CdCl(2) and the ligand 2,2'-bibenzimidazole.The mol-ecule lies on an inversion center and the metal center displays a strongly distorted trigonal-bipyramidal geometry.The crystal structure involves inter-molecular N-H⋯Cl hydrogen bonds, resulting in a one-dimensional supra-molecular structure.

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Affiliation: Chifeng University, Chifeng 024000, People's Republic of China.

ABSTRACT
The title binuclear complex, [Cd(2)Cl(4)(C(14)H(10)N(4))(2)], was synthesized by the hydro-thermal reaction of CdCl(2) and the ligand 2,2'-bibenzimidazole. The mol-ecule lies on an inversion center and the metal center displays a strongly distorted trigonal-bipyramidal geometry. The Cd(II) ions are coordinated by two N atoms from the organic ligand, and by one terminal and two bridging chloride anions. The crystal structure involves inter-molecular N-H⋯Cl hydrogen bonds, resulting in a one-dimensional supra-molecular structure.

No MeSH data available.


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One dimensional chain formed by hydrogen bonds (dashed lines) in the crystal structure of the title compound.
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Fap2: One dimensional chain formed by hydrogen bonds (dashed lines) in the crystal structure of the title compound.


Di-μ-chlorido-bis-[(2,2'-bibenzimidazole)chloridocadmium(II)].

Liu G - Acta Crystallogr Sect E Struct Rep Online (2008)

One dimensional chain formed by hydrogen bonds (dashed lines) in the crystal structure of the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967883&req=5

Fap2: One dimensional chain formed by hydrogen bonds (dashed lines) in the crystal structure of the title compound.
Bottom Line: The title binuclear complex, [Cd(2)Cl(4)(C(14)H(10)N(4))(2)], was synthesized by the hydro-thermal reaction of CdCl(2) and the ligand 2,2'-bibenzimidazole.The mol-ecule lies on an inversion center and the metal center displays a strongly distorted trigonal-bipyramidal geometry.The crystal structure involves inter-molecular N-H⋯Cl hydrogen bonds, resulting in a one-dimensional supra-molecular structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chifeng University, Chifeng 024000, People's Republic of China.

ABSTRACT
The title binuclear complex, [Cd(2)Cl(4)(C(14)H(10)N(4))(2)], was synthesized by the hydro-thermal reaction of CdCl(2) and the ligand 2,2'-bibenzimidazole. The mol-ecule lies on an inversion center and the metal center displays a strongly distorted trigonal-bipyramidal geometry. The Cd(II) ions are coordinated by two N atoms from the organic ligand, and by one terminal and two bridging chloride anions. The crystal structure involves inter-molecular N-H⋯Cl hydrogen bonds, resulting in a one-dimensional supra-molecular structure.

No MeSH data available.


Related in: MedlinePlus