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catena-Poly[[trimethyl-tin(IV)]-μ-2-(3-thien-yl)acetato].

Yang M, Yin H, Wen L, Li W, Wang D - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: There are two mol-ecules of the complex in the asymmetric unit.The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal.The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799 (9)/0.201 (9) and 0.618 (7)/0.382 (7), respectively.

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Affiliation: College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

ABSTRACT
The title compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), forms an infinite chain structure parallel to [100]. There are two mol-ecules of the complex in the asymmetric unit. The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal. The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799 (9)/0.201 (9) and 0.618 (7)/0.382 (7), respectively.

No MeSH data available.


The molecular structure of (I), showing 50% probability displacement ellipsoids and the atom-numbering scheme. H atoms have been omitted for clarity.
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Fap1: The molecular structure of (I), showing 50% probability displacement ellipsoids and the atom-numbering scheme. H atoms have been omitted for clarity.


catena-Poly[[trimethyl-tin(IV)]-μ-2-(3-thien-yl)acetato].

Yang M, Yin H, Wen L, Li W, Wang D - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of (I), showing 50% probability displacement ellipsoids and the atom-numbering scheme. H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967881&req=5

Fap1: The molecular structure of (I), showing 50% probability displacement ellipsoids and the atom-numbering scheme. H atoms have been omitted for clarity.
Bottom Line: There are two mol-ecules of the complex in the asymmetric unit.The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal.The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799 (9)/0.201 (9) and 0.618 (7)/0.382 (7), respectively.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

ABSTRACT
The title compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), forms an infinite chain structure parallel to [100]. There are two mol-ecules of the complex in the asymmetric unit. The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal. The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799 (9)/0.201 (9) and 0.618 (7)/0.382 (7), respectively.

No MeSH data available.