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Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole]bis-[dichloridocopper(II)].

Wang Z, Liu C, Zhang X, Gong X - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The asymmetric unit of the title compound, [Cu(2)Cl(4)(C(15)H(14)N(4))(2)], contains two halves of two centrosymmetric dinuclear mol-ecules, A and B.The conformations of the two crystallographically independent mol-ecules are slightly different: in A, the Cu⋯Cu separation is 4.174 (9) Å and the dihedral angle between the triazole and phenyl rings is 74.23 (11)°; these values are 4.137 (9) Å and 68.58 (13)°, respectively, in B.The crystal packing exhibits weak inter-molecular C-H⋯Cl inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, [Cu(2)Cl(4)(C(15)H(14)N(4))(2)], contains two halves of two centrosymmetric dinuclear mol-ecules, A and B. The conformations of the two crystallographically independent mol-ecules are slightly different: in A, the Cu⋯Cu separation is 4.174 (9) Å and the dihedral angle between the triazole and phenyl rings is 74.23 (11)°; these values are 4.137 (9) Å and 68.58 (13)°, respectively, in B. In each mol-ecule, the copper(II) ions have a distorted trigonal-bipyramidal coordination geometry with a CuCl(2)NN'N'' chromophore. The crystal packing exhibits weak inter-molecular C-H⋯Cl inter-actions.

No MeSH data available.


Related in: MedlinePlus

View of (I) with the atomic labelling and 30% probability displacement ellipsoids [symmetry codes: (i) -x + 1,-y + 2,-z; (ii) -x,-y + 1,-z + 1.
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Fap1: View of (I) with the atomic labelling and 30% probability displacement ellipsoids [symmetry codes: (i) -x + 1,-y + 2,-z; (ii) -x,-y + 1,-z + 1.


Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole]bis-[dichloridocopper(II)].

Wang Z, Liu C, Zhang X, Gong X - Acta Crystallogr Sect E Struct Rep Online (2008)

View of (I) with the atomic labelling and 30% probability displacement ellipsoids [symmetry codes: (i) -x + 1,-y + 2,-z; (ii) -x,-y + 1,-z + 1.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967870&req=5

Fap1: View of (I) with the atomic labelling and 30% probability displacement ellipsoids [symmetry codes: (i) -x + 1,-y + 2,-z; (ii) -x,-y + 1,-z + 1.
Bottom Line: The asymmetric unit of the title compound, [Cu(2)Cl(4)(C(15)H(14)N(4))(2)], contains two halves of two centrosymmetric dinuclear mol-ecules, A and B.The conformations of the two crystallographically independent mol-ecules are slightly different: in A, the Cu⋯Cu separation is 4.174 (9) Å and the dihedral angle between the triazole and phenyl rings is 74.23 (11)°; these values are 4.137 (9) Å and 68.58 (13)°, respectively, in B.The crystal packing exhibits weak inter-molecular C-H⋯Cl inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, [Cu(2)Cl(4)(C(15)H(14)N(4))(2)], contains two halves of two centrosymmetric dinuclear mol-ecules, A and B. The conformations of the two crystallographically independent mol-ecules are slightly different: in A, the Cu⋯Cu separation is 4.174 (9) Å and the dihedral angle between the triazole and phenyl rings is 74.23 (11)°; these values are 4.137 (9) Å and 68.58 (13)°, respectively, in B. In each mol-ecule, the copper(II) ions have a distorted trigonal-bipyramidal coordination geometry with a CuCl(2)NN'N'' chromophore. The crystal packing exhibits weak inter-molecular C-H⋯Cl inter-actions.

No MeSH data available.


Related in: MedlinePlus