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(2,2'-Bipyridine)(2-formyl-6-methoxy-phenolato)nickel(II) perchlorate.

Wang CJ, Ren PD, Wu WP, Zhang ZB - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17 (8)°.One of the O atoms of the perchlorate anion is involved in a weak inter-action with the Ni atom, with an Ni-O distance of 2.5732 (18) Å.The packing is stabilized by weak C-H⋯O inter-actions.

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ABSTRACT
In the title compound, [Ni(C(8)H(7)O(3))(C(10)H(8)N(2))]ClO(4), the Ni(II) atom is in a slightly distorted square-planar coordination by two N atoms from the 2,2'-bipyridine (bipy) ligand and two O atoms from the deprotonated 2-formyl-6-methoxy-phenolate (mbd) ligand. The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17 (8)°. One of the O atoms of the perchlorate anion is involved in a weak inter-action with the Ni atom, with an Ni-O distance of 2.5732 (18) Å. The packing is stabilized by weak C-H⋯O inter-actions.

No MeSH data available.


Molecular view of compound (I) with the atom-labeling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii.
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Fap1: Molecular view of compound (I) with the atom-labeling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii.


(2,2'-Bipyridine)(2-formyl-6-methoxy-phenolato)nickel(II) perchlorate.

Wang CJ, Ren PD, Wu WP, Zhang ZB - Acta Crystallogr Sect E Struct Rep Online (2008)

Molecular view of compound (I) with the atom-labeling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2967862&req=5

Fap1: Molecular view of compound (I) with the atom-labeling scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms are represented as small spheres of arbitrary radii.
Bottom Line: The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17 (8)°.One of the O atoms of the perchlorate anion is involved in a weak inter-action with the Ni atom, with an Ni-O distance of 2.5732 (18) Å.The packing is stabilized by weak C-H⋯O inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Ni(C(8)H(7)O(3))(C(10)H(8)N(2))]ClO(4), the Ni(II) atom is in a slightly distorted square-planar coordination by two N atoms from the 2,2'-bipyridine (bipy) ligand and two O atoms from the deprotonated 2-formyl-6-methoxy-phenolate (mbd) ligand. The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17 (8)°. One of the O atoms of the perchlorate anion is involved in a weak inter-action with the Ni atom, with an Ni-O distance of 2.5732 (18) Å. The packing is stabilized by weak C-H⋯O inter-actions.

No MeSH data available.