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Hexaaqua-dibromidoeuropium(III) bromide, [EuBr(2)(H(2)O)(6)]Br.

Hoch C, Simon A - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound crystallizes with the GdCl(3)·6H(2)O structure type, exhibiting discrete [EuBr(2)(H(2)O)(6)](+) cations as the main building blocks, linked with isolated bromide anions via H⋯Br hydrogen bonds to form a complex framework.The Eu atom and one Br atom each lie on a twofold rotation axis.

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Affiliation: Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-70569 Stuttgart, Germany.

ABSTRACT
The title compound crystallizes with the GdCl(3)·6H(2)O structure type, exhibiting discrete [EuBr(2)(H(2)O)(6)](+) cations as the main building blocks, linked with isolated bromide anions via H⋯Br hydrogen bonds to form a complex framework. The Eu atom and one Br atom each lie on a twofold rotation axis.

No MeSH data available.


View of the H—Br contacts in [Eu(H2O)6Br(2)2]Br(1), left: four hydrogen bonds link Br1 to water molecules, right: six hydrogen bonds link Br2 to water molecules. All displacement ellipsoids are drawn at the 90% propability level. [Symmetry codes: (i) -x, y, 1/2 - z; (ii) -x, -y, -z; (iii) x, -y, 1/2 + z.]
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Fap2: View of the H—Br contacts in [Eu(H2O)6Br(2)2]Br(1), left: four hydrogen bonds link Br1 to water molecules, right: six hydrogen bonds link Br2 to water molecules. All displacement ellipsoids are drawn at the 90% propability level. [Symmetry codes: (i) -x, y, 1/2 - z; (ii) -x, -y, -z; (iii) x, -y, 1/2 + z.]


Hexaaqua-dibromidoeuropium(III) bromide, [EuBr(2)(H(2)O)(6)]Br.

Hoch C, Simon A - Acta Crystallogr Sect E Struct Rep Online (2008)

View of the H—Br contacts in [Eu(H2O)6Br(2)2]Br(1), left: four hydrogen bonds link Br1 to water molecules, right: six hydrogen bonds link Br2 to water molecules. All displacement ellipsoids are drawn at the 90% propability level. [Symmetry codes: (i) -x, y, 1/2 - z; (ii) -x, -y, -z; (iii) x, -y, 1/2 + z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961385&req=5

Fap2: View of the H—Br contacts in [Eu(H2O)6Br(2)2]Br(1), left: four hydrogen bonds link Br1 to water molecules, right: six hydrogen bonds link Br2 to water molecules. All displacement ellipsoids are drawn at the 90% propability level. [Symmetry codes: (i) -x, y, 1/2 - z; (ii) -x, -y, -z; (iii) x, -y, 1/2 + z.]
Bottom Line: The title compound crystallizes with the GdCl(3)·6H(2)O structure type, exhibiting discrete [EuBr(2)(H(2)O)(6)](+) cations as the main building blocks, linked with isolated bromide anions via H⋯Br hydrogen bonds to form a complex framework.The Eu atom and one Br atom each lie on a twofold rotation axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-70569 Stuttgart, Germany.

ABSTRACT
The title compound crystallizes with the GdCl(3)·6H(2)O structure type, exhibiting discrete [EuBr(2)(H(2)O)(6)](+) cations as the main building blocks, linked with isolated bromide anions via H⋯Br hydrogen bonds to form a complex framework. The Eu atom and one Br atom each lie on a twofold rotation axis.

No MeSH data available.