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(S)-2-(Pyrrolidinium-2-ylmethyl-sulfan-yl)pyridinium dibromide.

Zhang S, Wang Y, Xia A, Luo S - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The thio-ether group connects the pyridine ring and the 2-methyl-pyrrolidine group.Both pyrrolidine NH bonds form hydrogen bonds to the bromide anions.These hydrogen bonds link the cations and anions in a helical chain along the c axis.

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Affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China.

ABSTRACT
In the title compound, C(10)H(16)N(2)S(2+)·2Br(-), the pyrrolidine ring displays an envelope conformation, with the flap C atom lying 0.484 (5) Å out of the plane of the rest of the pyrrolidine ring. The thio-ether group connects the pyridine ring and the 2-methyl-pyrrolidine group. Both pyrrolidine NH bonds form hydrogen bonds to the bromide anions. These hydrogen bonds link the cations and anions in a helical chain along the c axis.

No MeSH data available.


Hydrogen bonding in the title compound. Symmetry codes: (i) 1-y, 1+x-y, -1/3+z; (ii) 1-y, 1+x-y, 2/3+z; (iii) -x+y, 1-x, 1/3+z.
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Fap2: Hydrogen bonding in the title compound. Symmetry codes: (i) 1-y, 1+x-y, -1/3+z; (ii) 1-y, 1+x-y, 2/3+z; (iii) -x+y, 1-x, 1/3+z.


(S)-2-(Pyrrolidinium-2-ylmethyl-sulfan-yl)pyridinium dibromide.

Zhang S, Wang Y, Xia A, Luo S - Acta Crystallogr Sect E Struct Rep Online (2008)

Hydrogen bonding in the title compound. Symmetry codes: (i) 1-y, 1+x-y, -1/3+z; (ii) 1-y, 1+x-y, 2/3+z; (iii) -x+y, 1-x, 1/3+z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961376&req=5

Fap2: Hydrogen bonding in the title compound. Symmetry codes: (i) 1-y, 1+x-y, -1/3+z; (ii) 1-y, 1+x-y, 2/3+z; (iii) -x+y, 1-x, 1/3+z.
Bottom Line: The thio-ether group connects the pyridine ring and the 2-methyl-pyrrolidine group.Both pyrrolidine NH bonds form hydrogen bonds to the bromide anions.These hydrogen bonds link the cations and anions in a helical chain along the c axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China.

ABSTRACT
In the title compound, C(10)H(16)N(2)S(2+)·2Br(-), the pyrrolidine ring displays an envelope conformation, with the flap C atom lying 0.484 (5) Å out of the plane of the rest of the pyrrolidine ring. The thio-ether group connects the pyridine ring and the 2-methyl-pyrrolidine group. Both pyrrolidine NH bonds form hydrogen bonds to the bromide anions. These hydrogen bonds link the cations and anions in a helical chain along the c axis.

No MeSH data available.