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{2,2'-[Ethyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}oxido-vanadium(IV).

Wang C, Yuan JH, Xie G, Yu MJ, Li J - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The asymmetric unit contains two mol-ecules.Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position.Weak C-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular structure.

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ABSTRACT
The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N'-bis-(salicyl-idene)ethyl-enediamine under hydro-thermal conditions. The asymmetric unit contains two mol-ecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular structure.

No MeSH data available.


The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.
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Fap1: The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.


{2,2'-[Ethyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}oxido-vanadium(IV).

Wang C, Yuan JH, Xie G, Yu MJ, Li J - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961374&req=5

Fap1: The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.
Bottom Line: The asymmetric unit contains two mol-ecules.Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position.Weak C-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular structure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N'-bis-(salicyl-idene)ethyl-enediamine under hydro-thermal conditions. The asymmetric unit contains two mol-ecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular structure.

No MeSH data available.