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Bis[(2-pyridylmeth-yl)(triisopropyl-silyl)amido]zinc(II)-toluene-tetra-hydro-furan (4/2/1).

Koch C, Görls H, Westerhausen M - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In each mol-ecule, the Zn atom is tetra-hedrally coordinated by four N atoms.The two mol-ecules differ in the orientation of the isopropyl groups.The mol-ecules show large N-Zn-N angles [143.0 (2) and 145.7 (2)° between the amide groups].

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Affiliation: Institute of Inorganic and Analytical Chemistry, Friedrich-Schiller-Universität Jena, August-Bebel-Strasse 2, D-07743 Jena, Germany.

ABSTRACT
The transamination reaction of (2-pyridylmeth-yl)(triiso-propyl-silyl)amine with bis-{bis-(trimethyl-silyl)amido}zinc(II) yields the colorless title solvate, [Zn(C(15)H(27)N(2)Si)(2)]·0.5C(7)H(8)·0.25C(4)H(8)O. The title compound was crystallized from toluene and tetra-hydro-furan. There are two independent mol-ecules in the asymmetric unit. In each mol-ecule, the Zn atom is tetra-hedrally coordinated by four N atoms. The two mol-ecules differ in the orientation of the isopropyl groups. The mol-ecules show large N-Zn-N angles [143.0 (2) and 145.7 (2)° between the amide groups].

No MeSH data available.


The molecular structure of 1, showing 40% probability displacement ellipsoids and the atom-numbering scheme for molecule B H atoms have been omitted for clarity.
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Fap2: The molecular structure of 1, showing 40% probability displacement ellipsoids and the atom-numbering scheme for molecule B H atoms have been omitted for clarity.


Bis[(2-pyridylmeth-yl)(triisopropyl-silyl)amido]zinc(II)-toluene-tetra-hydro-furan (4/2/1).

Koch C, Görls H, Westerhausen M - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of 1, showing 40% probability displacement ellipsoids and the atom-numbering scheme for molecule B H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961323&req=5

Fap2: The molecular structure of 1, showing 40% probability displacement ellipsoids and the atom-numbering scheme for molecule B H atoms have been omitted for clarity.
Bottom Line: In each mol-ecule, the Zn atom is tetra-hedrally coordinated by four N atoms.The two mol-ecules differ in the orientation of the isopropyl groups.The mol-ecules show large N-Zn-N angles [143.0 (2) and 145.7 (2)° between the amide groups].

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of Inorganic and Analytical Chemistry, Friedrich-Schiller-Universität Jena, August-Bebel-Strasse 2, D-07743 Jena, Germany.

ABSTRACT
The transamination reaction of (2-pyridylmeth-yl)(triiso-propyl-silyl)amine with bis-{bis-(trimethyl-silyl)amido}zinc(II) yields the colorless title solvate, [Zn(C(15)H(27)N(2)Si)(2)]·0.5C(7)H(8)·0.25C(4)H(8)O. The title compound was crystallized from toluene and tetra-hydro-furan. There are two independent mol-ecules in the asymmetric unit. In each mol-ecule, the Zn atom is tetra-hedrally coordinated by four N atoms. The two mol-ecules differ in the orientation of the isopropyl groups. The mol-ecules show large N-Zn-N angles [143.0 (2) and 145.7 (2)° between the amide groups].

No MeSH data available.