Limits...
2,5,7-Trimethyl-3-phenyl-sulfonyl-1-benzofuran.

Choi HD, Seo PJ, Son BW, Lee U - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, C(17)H(16)O(3)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid.The phenyl ring exhibits a dihedral angle of 81.16 (4)° with the plane of the benzofuran fragment.In addition, the crystal structure exhibits intra- and inter-molecular C-H⋯O inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(17)H(16)O(3)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid. The phenyl ring exhibits a dihedral angle of 81.16 (4)° with the plane of the benzofuran fragment. The crystal structure is stabilized by π-π inter-actions between the furan and benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.874 (2) Å] and by C-H⋯π inter-actions between a phenyl H atom of the phenyl-sulfonyl substituent and the furan ring of adjacent mol-ecules. In addition, the crystal structure exhibits intra- and inter-molecular C-H⋯O inter-actions.

No MeSH data available.


Related in: MedlinePlus

π—π, C—H···π and C—H···O interactions (dotted lines) in the title compound. Cg denotes the ring centroid. [Symmetry code: (i) -x + 1, -y + 2, -z; (ii) -x + 2, -y + 1, -z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2961306&req=5

Fap2: π—π, C—H···π and C—H···O interactions (dotted lines) in the title compound. Cg denotes the ring centroid. [Symmetry code: (i) -x + 1, -y + 2, -z; (ii) -x + 2, -y + 1, -z.]


2,5,7-Trimethyl-3-phenyl-sulfonyl-1-benzofuran.

Choi HD, Seo PJ, Son BW, Lee U - Acta Crystallogr Sect E Struct Rep Online (2008)

π—π, C—H···π and C—H···O interactions (dotted lines) in the title compound. Cg denotes the ring centroid. [Symmetry code: (i) -x + 1, -y + 2, -z; (ii) -x + 2, -y + 1, -z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961306&req=5

Fap2: π—π, C—H···π and C—H···O interactions (dotted lines) in the title compound. Cg denotes the ring centroid. [Symmetry code: (i) -x + 1, -y + 2, -z; (ii) -x + 2, -y + 1, -z.]
Bottom Line: The title compound, C(17)H(16)O(3)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid.The phenyl ring exhibits a dihedral angle of 81.16 (4)° with the plane of the benzofuran fragment.In addition, the crystal structure exhibits intra- and inter-molecular C-H⋯O inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(17)H(16)O(3)S, was prepared by the oxidation of 2,5,7-trimethyl-3-phenyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid. The phenyl ring exhibits a dihedral angle of 81.16 (4)° with the plane of the benzofuran fragment. The crystal structure is stabilized by π-π inter-actions between the furan and benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.874 (2) Å] and by C-H⋯π inter-actions between a phenyl H atom of the phenyl-sulfonyl substituent and the furan ring of adjacent mol-ecules. In addition, the crystal structure exhibits intra- and inter-molecular C-H⋯O inter-actions.

No MeSH data available.


Related in: MedlinePlus