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μ-1,2-Di-4-pyridylethane-κN:N'-bis-[bis-(N,N-diisopropyl-dithio-carbamato-κS,S')zinc(II)].

Avila V, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal-bipyramidal ZnNS(4) geometry.The crystal structure involves intermolecular C-H⋯S hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA.

ABSTRACT
In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal-bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C-H⋯S hydrogen bonds.

No MeSH data available.


The molecular structure of (I) showing atom labelling scheme and displacement ellipsoids at the 50% probability level (arbitrary spheres for the H atoms). For clarity only the first atom of consecutively numbered iso-propyl groups and the N and two C atoms of the bispyridylethane ligand have been numbered.
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Fap1: The molecular structure of (I) showing atom labelling scheme and displacement ellipsoids at the 50% probability level (arbitrary spheres for the H atoms). For clarity only the first atom of consecutively numbered iso-propyl groups and the N and two C atoms of the bispyridylethane ligand have been numbered.


μ-1,2-Di-4-pyridylethane-κN:N'-bis-[bis-(N,N-diisopropyl-dithio-carbamato-κS,S')zinc(II)].

Avila V, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of (I) showing atom labelling scheme and displacement ellipsoids at the 50% probability level (arbitrary spheres for the H atoms). For clarity only the first atom of consecutively numbered iso-propyl groups and the N and two C atoms of the bispyridylethane ligand have been numbered.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961305&req=5

Fap1: The molecular structure of (I) showing atom labelling scheme and displacement ellipsoids at the 50% probability level (arbitrary spheres for the H atoms). For clarity only the first atom of consecutively numbered iso-propyl groups and the N and two C atoms of the bispyridylethane ligand have been numbered.
Bottom Line: In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal-bipyramidal ZnNS(4) geometry.The crystal structure involves intermolecular C-H⋯S hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA.

ABSTRACT
In the dinuclear title compound, [Zn{S(2)CN(n-Pr)(2)}(2){(NC(5)H(4))CH(2)CH(2)(C(5)H(4)N)}] or [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(12)N(2))], each Zn atom adopts a distorted trigonal-bipyramidal ZnNS(4) geometry. The crystal structure involves intermolecular C-H⋯S hydrogen bonds.

No MeSH data available.