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3,5,7-Tripropyl-1-aza-adamantane-4,6,10-triol.

Saaidi PL, Chazal PE, Maurin P, Jeanneau E, Hasserodt J - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, C(18)H(33)NO(3), was prepared according to a highly diastereoselective hydrogenation procedure from 3,5,7-triallyl-1-aza-adamantane-4,6,10-trione.The crystal structure of the title compound contains two crystallographically independent mol-ecules (Z' = 2), which are linked by inter-molecular hydrogen bonding into chains.In contrast to the aza-adamantanones, the aza-adamantanetriol core of the title compound does not show any particular C-C bond elongation.

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ABSTRACT
The title compound, C(18)H(33)NO(3), was prepared according to a highly diastereoselective hydrogenation procedure from 3,5,7-triallyl-1-aza-adamantane-4,6,10-trione. The crystal structure of the title compound contains two crystallographically independent mol-ecules (Z' = 2), which are linked by inter-molecular hydrogen bonding into chains. In contrast to the aza-adamantanones, the aza-adamantanetriol core of the title compound does not show any particular C-C bond elongation.

No MeSH data available.


Molecule A of the title compound with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omitted fo clarity.
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Fap1: Molecule A of the title compound with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omitted fo clarity.


3,5,7-Tripropyl-1-aza-adamantane-4,6,10-triol.

Saaidi PL, Chazal PE, Maurin P, Jeanneau E, Hasserodt J - Acta Crystallogr Sect E Struct Rep Online (2008)

Molecule A of the title compound with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omitted fo clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961298&req=5

Fap1: Molecule A of the title compound with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omitted fo clarity.
Bottom Line: The title compound, C(18)H(33)NO(3), was prepared according to a highly diastereoselective hydrogenation procedure from 3,5,7-triallyl-1-aza-adamantane-4,6,10-trione.The crystal structure of the title compound contains two crystallographically independent mol-ecules (Z' = 2), which are linked by inter-molecular hydrogen bonding into chains.In contrast to the aza-adamantanones, the aza-adamantanetriol core of the title compound does not show any particular C-C bond elongation.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(18)H(33)NO(3), was prepared according to a highly diastereoselective hydrogenation procedure from 3,5,7-triallyl-1-aza-adamantane-4,6,10-trione. The crystal structure of the title compound contains two crystallographically independent mol-ecules (Z' = 2), which are linked by inter-molecular hydrogen bonding into chains. In contrast to the aza-adamantanones, the aza-adamantanetriol core of the title compound does not show any particular C-C bond elongation.

No MeSH data available.