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(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra-azacyclo-tetra-deca-ne)nickel(II) bis-(O,O'-dibenzyl dithio-phosphate).

Xie B, Zou LK, He YG, Feng JS, Zhang XL - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms.The two O,O'-bis-(2-phenyl-meth-yl) dithio-phosphate anions act as counter-ions to balance the charge and they inter-act with the complex through N-H⋯S hydrogen bonds.Important geometric data include Ni-N distances of 1.958 (3) and 1.963 (3) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Sichuan University of Science & Engineering, Zigong, Sichuan 643000, People's Republic of China.

ABSTRACT
In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms. The two O,O'-bis-(2-phenyl-meth-yl) dithio-phosphate anions act as counter-ions to balance the charge and they inter-act with the complex through N-H⋯S hydrogen bonds. Important geometric data include Ni-N distances of 1.958 (3) and 1.963 (3) Å.

No MeSH data available.


Related in: MedlinePlus

A View of the title compound showing the atom-labelling scheme.Only one of the two anions is represented for clarity.Displacement ellipsoids are drawn at the 30% probability level. Hydrogen-bonds are shown as dashed lines. For the sake of clarity, H atoms bonded to C atoms have been omitted. H atoms are represented as small spheres of arbitrary radii. [Symmetry code: (i) -x + 1, -y + 1, -z].
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Fap1: A View of the title compound showing the atom-labelling scheme.Only one of the two anions is represented for clarity.Displacement ellipsoids are drawn at the 30% probability level. Hydrogen-bonds are shown as dashed lines. For the sake of clarity, H atoms bonded to C atoms have been omitted. H atoms are represented as small spheres of arbitrary radii. [Symmetry code: (i) -x + 1, -y + 1, -z].


(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra-azacyclo-tetra-deca-ne)nickel(II) bis-(O,O'-dibenzyl dithio-phosphate).

Xie B, Zou LK, He YG, Feng JS, Zhang XL - Acta Crystallogr Sect E Struct Rep Online (2008)

A View of the title compound showing the atom-labelling scheme.Only one of the two anions is represented for clarity.Displacement ellipsoids are drawn at the 30% probability level. Hydrogen-bonds are shown as dashed lines. For the sake of clarity, H atoms bonded to C atoms have been omitted. H atoms are represented as small spheres of arbitrary radii. [Symmetry code: (i) -x + 1, -y + 1, -z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961295&req=5

Fap1: A View of the title compound showing the atom-labelling scheme.Only one of the two anions is represented for clarity.Displacement ellipsoids are drawn at the 30% probability level. Hydrogen-bonds are shown as dashed lines. For the sake of clarity, H atoms bonded to C atoms have been omitted. H atoms are represented as small spheres of arbitrary radii. [Symmetry code: (i) -x + 1, -y + 1, -z].
Bottom Line: In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms.The two O,O'-bis-(2-phenyl-meth-yl) dithio-phosphate anions act as counter-ions to balance the charge and they inter-act with the complex through N-H⋯S hydrogen bonds.Important geometric data include Ni-N distances of 1.958 (3) and 1.963 (3) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Sichuan University of Science & Engineering, Zigong, Sichuan 643000, People's Republic of China.

ABSTRACT
In the title salt-type 1:2 adduct, [Ni(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2) or [Ni(tet-a)][S(2)P(OCH(2)Ph)(2)](2), where tet-a is meso-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane, the [Ni(tet-a)](2+) complex cation exhibits a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four macrocyclic N atoms. The two O,O'-bis-(2-phenyl-meth-yl) dithio-phosphate anions act as counter-ions to balance the charge and they inter-act with the complex through N-H⋯S hydrogen bonds. Important geometric data include Ni-N distances of 1.958 (3) and 1.963 (3) Å.

No MeSH data available.


Related in: MedlinePlus