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Bis(benzo-15-crown-5-κO)strontium bis-(triiodide).

Walbaum C, Pantenburg I, Meyer G - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro-methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (-) anions which are arranged in alternating layers parallel to (010).The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, D-50939 Köln, Germany.

ABSTRACT
The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro-methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (-) anions which are arranged in alternating layers parallel to (010). The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.

No MeSH data available.


Related in: MedlinePlus

A projection of the structure of [Sr(benzo-15-crown-5)2](I3)2 along the ab plane. Hydrogen atoms are omitted for clarity.
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Fap2: A projection of the structure of [Sr(benzo-15-crown-5)2](I3)2 along the ab plane. Hydrogen atoms are omitted for clarity.


Bis(benzo-15-crown-5-κO)strontium bis-(triiodide).

Walbaum C, Pantenburg I, Meyer G - Acta Crystallogr Sect E Struct Rep Online (2008)

A projection of the structure of [Sr(benzo-15-crown-5)2](I3)2 along the ab plane. Hydrogen atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961288&req=5

Fap2: A projection of the structure of [Sr(benzo-15-crown-5)2](I3)2 along the ab plane. Hydrogen atoms are omitted for clarity.
Bottom Line: The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro-methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (-) anions which are arranged in alternating layers parallel to (010).The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, D-50939 Köln, Germany.

ABSTRACT
The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro-methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (-) anions which are arranged in alternating layers parallel to (010). The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.

No MeSH data available.


Related in: MedlinePlus