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[1,2-Bis(diphenyl-phosphino)ethane]{2-[bis-(diphenyl-phosphinometh-yl)amino]pyridinium}fluoridohydrazidato-molybdenum(IV) bis-(tetra-fluoridoborate).

Stephan G, Näther C, Tuczek F - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis-(diphenyl-phosphino)ethane and one 2-[bis-(diphenyl-phosphinometh-yl)amino]pyridinium ligand.The remaining binding sites of the distorted octa-hedron are occupied by a hydrazidate (NNH(2) (2-)) and a fluoride ligand.Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

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Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstrasse 40, D-24098 Kiel, Germany.

ABSTRACT
In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis-(diphenyl-phosphino)ethane and one 2-[bis-(diphenyl-phosphinometh-yl)amino]pyridinium ligand. The remaining binding sites of the distorted octa-hedron are occupied by a hydrazidate (NNH(2) (2-)) and a fluoride ligand. Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

No MeSH data available.


: Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. The H atoms are omitted for clarity.
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Fap1: : Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. The H atoms are omitted for clarity.


[1,2-Bis(diphenyl-phosphino)ethane]{2-[bis-(diphenyl-phosphinometh-yl)amino]pyridinium}fluoridohydrazidato-molybdenum(IV) bis-(tetra-fluoridoborate).

Stephan G, Näther C, Tuczek F - Acta Crystallogr Sect E Struct Rep Online (2008)

: Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. The H atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961270&req=5

Fap1: : Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. The H atoms are omitted for clarity.
Bottom Line: In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis-(diphenyl-phosphino)ethane and one 2-[bis-(diphenyl-phosphinometh-yl)amino]pyridinium ligand.The remaining binding sites of the distorted octa-hedron are occupied by a hydrazidate (NNH(2) (2-)) and a fluoride ligand.Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstrasse 40, D-24098 Kiel, Germany.

ABSTRACT
In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis-(diphenyl-phosphino)ethane and one 2-[bis-(diphenyl-phosphinometh-yl)amino]pyridinium ligand. The remaining binding sites of the distorted octa-hedron are occupied by a hydrazidate (NNH(2) (2-)) and a fluoride ligand. Two F atoms of an anion are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

No MeSH data available.