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Poly[[μ(4)-naphthalene-1,4-dicarboxyl-ato-κO:O':O'':O'''-μ(2)-naphthalene-1,4-dicarboxyl-ato-κO,O':O'',O'''-bis-(2-phenyl-1H-1,3,7,8-tetra-azacyclopenta-[l]phenanthrene-κN,N)dimanganese(II)] N,N-dimethyl-formamide solvate].

Li HD, Liu Y, Xu ML, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: One of the two 1,4-dicarboxyl-ate dianions in the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(19)H(12)N(4))(2)]·C(3)H(7)NO, uses its two carboxyl-ate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxyl-ate dianion binds to four such metal centers.The octa-hedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethyl-formamide mol-ecules occupy the spaces between adjacent layers.Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.

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ABSTRACT
One of the two 1,4-dicarboxyl-ate dianions in the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(19)H(12)N(4))(2)]·C(3)H(7)NO, uses its two carboxyl-ate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxyl-ate dianion binds to four such metal centers. The octa-hedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethyl-formamide mol-ecules occupy the spaces between adjacent layers. Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.

No MeSH data available.


Layer structure of the manganese-naphthalene-1,4-dicarboxylate network as illustrated by OLEX (Dolomanov et al., 2003).
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Fap2: Layer structure of the manganese-naphthalene-1,4-dicarboxylate network as illustrated by OLEX (Dolomanov et al., 2003).


Poly[[μ(4)-naphthalene-1,4-dicarboxyl-ato-κO:O':O'':O'''-μ(2)-naphthalene-1,4-dicarboxyl-ato-κO,O':O'',O'''-bis-(2-phenyl-1H-1,3,7,8-tetra-azacyclopenta-[l]phenanthrene-κN,N)dimanganese(II)] N,N-dimethyl-formamide solvate].

Li HD, Liu Y, Xu ML, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Layer structure of the manganese-naphthalene-1,4-dicarboxylate network as illustrated by OLEX (Dolomanov et al., 2003).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961267&req=5

Fap2: Layer structure of the manganese-naphthalene-1,4-dicarboxylate network as illustrated by OLEX (Dolomanov et al., 2003).
Bottom Line: One of the two 1,4-dicarboxyl-ate dianions in the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(19)H(12)N(4))(2)]·C(3)H(7)NO, uses its two carboxyl-ate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxyl-ate dianion binds to four such metal centers.The octa-hedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethyl-formamide mol-ecules occupy the spaces between adjacent layers.Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
One of the two 1,4-dicarboxyl-ate dianions in the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(19)H(12)N(4))(2)]·C(3)H(7)NO, uses its two carboxyl-ate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxyl-ate dianion binds to four such metal centers. The octa-hedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethyl-formamide mol-ecules occupy the spaces between adjacent layers. Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.

No MeSH data available.