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Poly[di-μ(5)-adipato-κO:O':O'':O''',O'''-μ(4)-adipato-κO:O':O'':O'''-bis-[2-phenyl-1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthrene-κN,N]tricobalt(II)].

Xu ML, Zhou R, Wang GY, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2-)) occupy general positions and two are situated on different inversion centres.Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms.The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N-H⋯O hydrogen bonds.

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ABSTRACT
In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2-)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

Thermal ellipsoid plot of a portion of polymeric Co3(C19H12N4)2(C6H8O4)3; displacement ellipsoids are drawn at the 50% probability level, and H atoms as spheres of arbitrary radii. Symmetry codes are given in Table 1.
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Fap1: Thermal ellipsoid plot of a portion of polymeric Co3(C19H12N4)2(C6H8O4)3; displacement ellipsoids are drawn at the 50% probability level, and H atoms as spheres of arbitrary radii. Symmetry codes are given in Table 1.


Poly[di-μ(5)-adipato-κO:O':O'':O''',O'''-μ(4)-adipato-κO:O':O'':O'''-bis-[2-phenyl-1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthrene-κN,N]tricobalt(II)].

Xu ML, Zhou R, Wang GY, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Thermal ellipsoid plot of a portion of polymeric Co3(C19H12N4)2(C6H8O4)3; displacement ellipsoids are drawn at the 50% probability level, and H atoms as spheres of arbitrary radii. Symmetry codes are given in Table 1.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961260&req=5

Fap1: Thermal ellipsoid plot of a portion of polymeric Co3(C19H12N4)2(C6H8O4)3; displacement ellipsoids are drawn at the 50% probability level, and H atoms as spheres of arbitrary radii. Symmetry codes are given in Table 1.
Bottom Line: In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2-)) occupy general positions and two are situated on different inversion centres.Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms.The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2-)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of the three Co atoms, two are chelated by N-heterocycles; the third is bonded to six O atoms. The bonding mode of the dianion gives rise to a three-dimensional network structure; the network is further consolidated by N-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus