Limits...
Three-dimensional hydrogen-bonded supra-molecular assembly in tetrakis-(1,3,5-triaza-7-phosphaadamantane)copper(I) chloride hexa-hydrate.

Kirillov AM, Smoleński P, Guedes da Silva MF, Kopylovich MN, Pombeiro AJ - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The Cu(I) atom exhibits tetra-hedral coordination geometry, involving four symmetry-equivalent P-bound PTA ligands.The structure is extended to a regular three-dimensional supra-molecular framework via numerous equivalent O-H⋯N hydrogen bonds between all solvent water mol-ecules (six per cation) and all PTA N atoms, thus simultaneously bridging each [Cu(PTA)(4)](+) cation with 12 neighbouring units in multiple directions.The study also shows that PTA can be a convenient ligand in crystal engineering for the construction of supra-molecular architectures.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The structure of the title compound, [Cu(PTA)(4)]Cl·6H(2)O (PTA is 1,3,5-triaza-7-phosphaadamantane, C(6)H(12)N(3)P), is composed of discrete monomeric [Cu(PTA)(4)](+) cations, chloride anions and uncoordinated water mol-ecules. The Cu(I) atom exhibits tetra-hedral coordination geometry, involving four symmetry-equivalent P-bound PTA ligands. The structure is extended to a regular three-dimensional supra-molecular framework via numerous equivalent O-H⋯N hydrogen bonds between all solvent water mol-ecules (six per cation) and all PTA N atoms, thus simultaneously bridging each [Cu(PTA)(4)](+) cation with 12 neighbouring units in multiple directions. The study also shows that PTA can be a convenient ligand in crystal engineering for the construction of supra-molecular architectures.

No MeSH data available.


Related in: MedlinePlus

Fragment of the crystal packing diagram of (I) showing the simultaneous multidimensional interlinkage of the central monomeric [Cu(PTA)4]+ unit (black coloured) with twelve neighbouring ones (each represented by different colour) via repeating O10—H10···N1 hydrogen bonding interactions (black dashed lines) between crystallization water molecules O10 (coloured balls) and PTA N1 atoms. H and Cl atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2961253&req=5

Fap2: Fragment of the crystal packing diagram of (I) showing the simultaneous multidimensional interlinkage of the central monomeric [Cu(PTA)4]+ unit (black coloured) with twelve neighbouring ones (each represented by different colour) via repeating O10—H10···N1 hydrogen bonding interactions (black dashed lines) between crystallization water molecules O10 (coloured balls) and PTA N1 atoms. H and Cl atoms are omitted for clarity.


Three-dimensional hydrogen-bonded supra-molecular assembly in tetrakis-(1,3,5-triaza-7-phosphaadamantane)copper(I) chloride hexa-hydrate.

Kirillov AM, Smoleński P, Guedes da Silva MF, Kopylovich MN, Pombeiro AJ - Acta Crystallogr Sect E Struct Rep Online (2008)

Fragment of the crystal packing diagram of (I) showing the simultaneous multidimensional interlinkage of the central monomeric [Cu(PTA)4]+ unit (black coloured) with twelve neighbouring ones (each represented by different colour) via repeating O10—H10···N1 hydrogen bonding interactions (black dashed lines) between crystallization water molecules O10 (coloured balls) and PTA N1 atoms. H and Cl atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961253&req=5

Fap2: Fragment of the crystal packing diagram of (I) showing the simultaneous multidimensional interlinkage of the central monomeric [Cu(PTA)4]+ unit (black coloured) with twelve neighbouring ones (each represented by different colour) via repeating O10—H10···N1 hydrogen bonding interactions (black dashed lines) between crystallization water molecules O10 (coloured balls) and PTA N1 atoms. H and Cl atoms are omitted for clarity.
Bottom Line: The Cu(I) atom exhibits tetra-hedral coordination geometry, involving four symmetry-equivalent P-bound PTA ligands.The structure is extended to a regular three-dimensional supra-molecular framework via numerous equivalent O-H⋯N hydrogen bonds between all solvent water mol-ecules (six per cation) and all PTA N atoms, thus simultaneously bridging each [Cu(PTA)(4)](+) cation with 12 neighbouring units in multiple directions.The study also shows that PTA can be a convenient ligand in crystal engineering for the construction of supra-molecular architectures.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The structure of the title compound, [Cu(PTA)(4)]Cl·6H(2)O (PTA is 1,3,5-triaza-7-phosphaadamantane, C(6)H(12)N(3)P), is composed of discrete monomeric [Cu(PTA)(4)](+) cations, chloride anions and uncoordinated water mol-ecules. The Cu(I) atom exhibits tetra-hedral coordination geometry, involving four symmetry-equivalent P-bound PTA ligands. The structure is extended to a regular three-dimensional supra-molecular framework via numerous equivalent O-H⋯N hydrogen bonds between all solvent water mol-ecules (six per cation) and all PTA N atoms, thus simultaneously bridging each [Cu(PTA)(4)](+) cation with 12 neighbouring units in multiple directions. The study also shows that PTA can be a convenient ligand in crystal engineering for the construction of supra-molecular architectures.

No MeSH data available.


Related in: MedlinePlus