Limits...
Tetra-aqua-bis(pyridine-3-sulfonato-κN)nickel(II).

Zhang BY, Nie JJ, Xu DJ - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the mol-ecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water mol-ecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octa-hedral geometry.The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π-π stacking between the pyridine rings.The structure also contains inter-molecular O-H⋯O hydrogen bonding and weak C-H⋯O hydrogen bonding.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China.

ABSTRACT
In the mol-ecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water mol-ecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octa-hedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π-π stacking between the pyridine rings. The structure also contains inter-molecular O-H⋯O hydrogen bonding and weak C-H⋯O hydrogen bonding.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound with 40% probability displacement (arbitrary spheres for H atoms) [symmetry codes: (i)1 - x,1 - y,1 - z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2961246&req=5

Fap1: The molecular structure of the title compound with 40% probability displacement (arbitrary spheres for H atoms) [symmetry codes: (i)1 - x,1 - y,1 - z].


Tetra-aqua-bis(pyridine-3-sulfonato-κN)nickel(II).

Zhang BY, Nie JJ, Xu DJ - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound with 40% probability displacement (arbitrary spheres for H atoms) [symmetry codes: (i)1 - x,1 - y,1 - z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961246&req=5

Fap1: The molecular structure of the title compound with 40% probability displacement (arbitrary spheres for H atoms) [symmetry codes: (i)1 - x,1 - y,1 - z].
Bottom Line: In the mol-ecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water mol-ecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octa-hedral geometry.The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π-π stacking between the pyridine rings.The structure also contains inter-molecular O-H⋯O hydrogen bonding and weak C-H⋯O hydrogen bonding.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China.

ABSTRACT
In the mol-ecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water mol-ecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octa-hedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π-π stacking between the pyridine rings. The structure also contains inter-molecular O-H⋯O hydrogen bonding and weak C-H⋯O hydrogen bonding.

No MeSH data available.


Related in: MedlinePlus