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2,2'-(Imino-dimethyl-ene)dibenz-imid-azol-ium bis-(perchlorate) methanol solvate.

Zhou CS, Huang XY, Meng XG - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°.The anions and solvent mol-ecules are linked to the cation by N-H⋯O hydrogen bonds.In the crystal structure, the combination of N-H⋯O and O-H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π-π inter-actions, forming a three-dimensional network.

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Affiliation: Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.

ABSTRACT
In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol-ecules are linked to the cation by N-H⋯O hydrogen bonds. In the crystal structure, the combination of N-H⋯O and O-H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π-π inter-actions, forming a three-dimensional network.

No MeSH data available.


Part of the crystal structure of the title compound, showing the formation of the two-dimensional network parallel to the (010) plane, built from N—H···O and O—H···O hydrogen bonds which are shown as dashed lines. (a) the view along the a axis and (b) the view along the b axis. For the sake of clarity, H atoms not involved in hydrogen bonding have been omitted.
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Fap2: Part of the crystal structure of the title compound, showing the formation of the two-dimensional network parallel to the (010) plane, built from N—H···O and O—H···O hydrogen bonds which are shown as dashed lines. (a) the view along the a axis and (b) the view along the b axis. For the sake of clarity, H atoms not involved in hydrogen bonding have been omitted.


2,2'-(Imino-dimethyl-ene)dibenz-imid-azol-ium bis-(perchlorate) methanol solvate.

Zhou CS, Huang XY, Meng XG - Acta Crystallogr Sect E Struct Rep Online (2008)

Part of the crystal structure of the title compound, showing the formation of the two-dimensional network parallel to the (010) plane, built from N—H···O and O—H···O hydrogen bonds which are shown as dashed lines. (a) the view along the a axis and (b) the view along the b axis. For the sake of clarity, H atoms not involved in hydrogen bonding have been omitted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961233&req=5

Fap2: Part of the crystal structure of the title compound, showing the formation of the two-dimensional network parallel to the (010) plane, built from N—H···O and O—H···O hydrogen bonds which are shown as dashed lines. (a) the view along the a axis and (b) the view along the b axis. For the sake of clarity, H atoms not involved in hydrogen bonding have been omitted.
Bottom Line: In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°.The anions and solvent mol-ecules are linked to the cation by N-H⋯O hydrogen bonds.In the crystal structure, the combination of N-H⋯O and O-H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π-π inter-actions, forming a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.

ABSTRACT
In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol-ecules are linked to the cation by N-H⋯O hydrogen bonds. In the crystal structure, the combination of N-H⋯O and O-H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π-π inter-actions, forming a three-dimensional network.

No MeSH data available.