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Di-μ-chlorido-bis-({9-[(2,6-diisopropyl-phen-yl)imino-meth-yl]anthracen-1-yl}palladium(II)).

Zhou J, Wang Q, Sun H - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C-H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro-methane as orange crystals.The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.

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Affiliation: School of Chemistry and Chemical Engineering, Shandong University, Shanda Nanlu 27, Jinan 250100, People's Republic of China.

ABSTRACT
The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C-H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro-methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.

No MeSH data available.


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Molecular structure of the title compound. Displacement ellipsoids are drawn at 30% probability level, symmetry code A: 0.5-X, 0.5+Y, 0.5-Z
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Fap1: Molecular structure of the title compound. Displacement ellipsoids are drawn at 30% probability level, symmetry code A: 0.5-X, 0.5+Y, 0.5-Z


Di-μ-chlorido-bis-({9-[(2,6-diisopropyl-phen-yl)imino-meth-yl]anthracen-1-yl}palladium(II)).

Zhou J, Wang Q, Sun H - Acta Crystallogr Sect E Struct Rep Online (2008)

Molecular structure of the title compound. Displacement ellipsoids are drawn at 30% probability level, symmetry code A: 0.5-X, 0.5+Y, 0.5-Z
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961217&req=5

Fap1: Molecular structure of the title compound. Displacement ellipsoids are drawn at 30% probability level, symmetry code A: 0.5-X, 0.5+Y, 0.5-Z
Bottom Line: The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C-H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro-methane as orange crystals.The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, Shandong University, Shanda Nanlu 27, Jinan 250100, People's Republic of China.

ABSTRACT
The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C-H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro-methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.

No MeSH data available.


Related in: MedlinePlus