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Dicyclo-hexyl-ammonium bis-(chloro-difluoro-acetato-κO)cyclo-pentyl-diphenyl-stannate(IV).

Teo YY, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The five-coordinate Sn atom in the title mixed organyl stannate compound, (C(12)H(24)N)[Sn(C(5)H(9))(C(6)H(5))(2)(C(2)ClF(2)O(2))], is in a trans-C(3)SnO(2) trigonal-bipyramidal coordination environment.The NH(2) groups of the cations act as hydrogen-bond donors to two symmetry-related anions, resulting in the formation of linear chains.One of the phenyl rings is disordered over two sites with equal occupancies.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The five-coordinate Sn atom in the title mixed organyl stannate compound, (C(12)H(24)N)[Sn(C(5)H(9))(C(6)H(5))(2)(C(2)ClF(2)O(2))], is in a trans-C(3)SnO(2) trigonal-bipyramidal coordination environment. The NH(2) groups of the cations act as hydrogen-bond donors to two symmetry-related anions, resulting in the formation of linear chains. One of the phenyl rings is disordered over two sites with equal occupancies.

No MeSH data available.


50% Probability thermal ellipsoid plot of the two independent formula units of [(C6H11)2NH2)] [Sn(C5H9)(C6H5)2(O2CClF2)2]. Hydrogen atoms are drawn as spheres of arbitrary radius. The disorder is not shown.
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Fap1: 50% Probability thermal ellipsoid plot of the two independent formula units of [(C6H11)2NH2)] [Sn(C5H9)(C6H5)2(O2CClF2)2]. Hydrogen atoms are drawn as spheres of arbitrary radius. The disorder is not shown.


Dicyclo-hexyl-ammonium bis-(chloro-difluoro-acetato-κO)cyclo-pentyl-diphenyl-stannate(IV).

Teo YY, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

50% Probability thermal ellipsoid plot of the two independent formula units of [(C6H11)2NH2)] [Sn(C5H9)(C6H5)2(O2CClF2)2]. Hydrogen atoms are drawn as spheres of arbitrary radius. The disorder is not shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961194&req=5

Fap1: 50% Probability thermal ellipsoid plot of the two independent formula units of [(C6H11)2NH2)] [Sn(C5H9)(C6H5)2(O2CClF2)2]. Hydrogen atoms are drawn as spheres of arbitrary radius. The disorder is not shown.
Bottom Line: The five-coordinate Sn atom in the title mixed organyl stannate compound, (C(12)H(24)N)[Sn(C(5)H(9))(C(6)H(5))(2)(C(2)ClF(2)O(2))], is in a trans-C(3)SnO(2) trigonal-bipyramidal coordination environment.The NH(2) groups of the cations act as hydrogen-bond donors to two symmetry-related anions, resulting in the formation of linear chains.One of the phenyl rings is disordered over two sites with equal occupancies.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
The five-coordinate Sn atom in the title mixed organyl stannate compound, (C(12)H(24)N)[Sn(C(5)H(9))(C(6)H(5))(2)(C(2)ClF(2)O(2))], is in a trans-C(3)SnO(2) trigonal-bipyramidal coordination environment. The NH(2) groups of the cations act as hydrogen-bond donors to two symmetry-related anions, resulting in the formation of linear chains. One of the phenyl rings is disordered over two sites with equal occupancies.

No MeSH data available.