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Tetra-kis(μ(3)-2-{[1,1-bis-(hydroxy-meth-yl)-2-oxidoeth-yl]imino-meth-yl}-6-methoxy-phenol-ato)tetra-nickel(II) tetra-hydrate.

Guo Y, Li L, Liu Y, Dong J, Wang D - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title complex, [Ni(4)(C(12)H(15)NO(4))(4)]·4H(2)O, has crystal-lographic fourfold inversion symmetry, with each Ni(II) ion coordinated in a slightly distorted square-pyramidal coordination environment and forming an Ni(4)O(4) cubane-like core.In the crystal structure, inter-molecular O-H⋯O hydrogen bonds connect complex and water mol-ecules to form a three-dimensional network.The O atom of one of the unique hydroxy-methyl groups is disordered over two sites, with the ratio of occupancies being approximately 0.79:0.21.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

ABSTRACT
The title complex, [Ni(4)(C(12)H(15)NO(4))(4)]·4H(2)O, has crystal-lographic fourfold inversion symmetry, with each Ni(II) ion coordinated in a slightly distorted square-pyramidal coordination environment and forming an Ni(4)O(4) cubane-like core. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds connect complex and water mol-ecules to form a three-dimensional network. The O atom of one of the unique hydroxy-methyl groups is disordered over two sites, with the ratio of occupancies being approximately 0.79:0.21.

No MeSH data available.


Related in: MedlinePlus

The structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme. The water solvent molecules are not shown. Open bonds indicate disordered atoms and only the assymetric unit is labelled.
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Fap1: The structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme. The water solvent molecules are not shown. Open bonds indicate disordered atoms and only the assymetric unit is labelled.


Tetra-kis(μ(3)-2-{[1,1-bis-(hydroxy-meth-yl)-2-oxidoeth-yl]imino-meth-yl}-6-methoxy-phenol-ato)tetra-nickel(II) tetra-hydrate.

Guo Y, Li L, Liu Y, Dong J, Wang D - Acta Crystallogr Sect E Struct Rep Online (2008)

The structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme. The water solvent molecules are not shown. Open bonds indicate disordered atoms and only the assymetric unit is labelled.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961190&req=5

Fap1: The structure of the title compound, showing 30% probability displacement ellipsoids and the atom-numbering scheme. The water solvent molecules are not shown. Open bonds indicate disordered atoms and only the assymetric unit is labelled.
Bottom Line: The title complex, [Ni(4)(C(12)H(15)NO(4))(4)]·4H(2)O, has crystal-lographic fourfold inversion symmetry, with each Ni(II) ion coordinated in a slightly distorted square-pyramidal coordination environment and forming an Ni(4)O(4) cubane-like core.In the crystal structure, inter-molecular O-H⋯O hydrogen bonds connect complex and water mol-ecules to form a three-dimensional network.The O atom of one of the unique hydroxy-methyl groups is disordered over two sites, with the ratio of occupancies being approximately 0.79:0.21.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

ABSTRACT
The title complex, [Ni(4)(C(12)H(15)NO(4))(4)]·4H(2)O, has crystal-lographic fourfold inversion symmetry, with each Ni(II) ion coordinated in a slightly distorted square-pyramidal coordination environment and forming an Ni(4)O(4) cubane-like core. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds connect complex and water mol-ecules to form a three-dimensional network. The O atom of one of the unique hydroxy-methyl groups is disordered over two sites, with the ratio of occupancies being approximately 0.79:0.21.

No MeSH data available.


Related in: MedlinePlus