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Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).

He YT - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion.The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry.The crystal packing is stabilized by N-H⋯O hydrogen bonds.

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Affiliation: Zhoukou Vocational and Technical College, Zhoukou Henan 466600, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion. The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry. The crystal packing is stabilized by N-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound, showing 30% probability displacement ellipsoids. Unlabelled atoms are related to labelled atoms by the symmetry operation (1 - x, 1 - y, 1 - z).
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Fap1: The molecular structure of the title compound, showing 30% probability displacement ellipsoids. Unlabelled atoms are related to labelled atoms by the symmetry operation (1 - x, 1 - y, 1 - z).


Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).

He YT - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound, showing 30% probability displacement ellipsoids. Unlabelled atoms are related to labelled atoms by the symmetry operation (1 - x, 1 - y, 1 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961174&req=5

Fap1: The molecular structure of the title compound, showing 30% probability displacement ellipsoids. Unlabelled atoms are related to labelled atoms by the symmetry operation (1 - x, 1 - y, 1 - z).
Bottom Line: The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion.The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry.The crystal packing is stabilized by N-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Zhoukou Vocational and Technical College, Zhoukou Henan 466600, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion. The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry. The crystal packing is stabilized by N-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus