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Hexakis(1H-imidazole-κN)mangan-ese(II) triaqua-tris(1H-imidazole-κN)manganese(II) bis-(naphthalene-1,4-dicarboxyl-ate).

Li JH, Nie JJ, Xu DJ - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the crystal structure of the title compound, [Mn(C(3)H(4)N(2))(6)][Mn(C(3)H(4)N(2))(3)(H(2)O)(3)](C(12)H(6)O(4))(2), there are uncoordinated naphthalene-dicarboxyl-ate dianions and two kinds of Mn(II) complex cations, both assuming a distorted octa-hedral geometry.One Mn(II) cation is located on an inversion center and is coordinated by six imidazole mol-ecules, while the other Mn(II) cation is located on a twofold rotation axis and is coordinated by three water mol-ecules and three imidazole units.The naphthalene-dicarboxyl-ate dianions are linked to both Mn(II) complex cations via O-H⋯O and N-H⋯O hydrogen bonding, but no π-π stacking is observed between aromatic rings in the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Zhejiang University, People's Republic of China.

ABSTRACT
In the crystal structure of the title compound, [Mn(C(3)H(4)N(2))(6)][Mn(C(3)H(4)N(2))(3)(H(2)O)(3)](C(12)H(6)O(4))(2), there are uncoordinated naphthalene-dicarboxyl-ate dianions and two kinds of Mn(II) complex cations, both assuming a distorted octa-hedral geometry. One Mn(II) cation is located on an inversion center and is coordinated by six imidazole mol-ecules, while the other Mn(II) cation is located on a twofold rotation axis and is coordinated by three water mol-ecules and three imidazole units. The naphthalene-dicarboxyl-ate dianions are linked to both Mn(II) complex cations via O-H⋯O and N-H⋯O hydrogen bonding, but no π-π stacking is observed between aromatic rings in the crystal structure.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound with 30% probability displacement (arbitrary spheres for H atoms). One of the disordered imidazole components is omitted for clarify. Dashed lines indicate hydrogen bonding [symmetry codes: (i) -x + 3/2, -y + 3/2, z; (ii) -x + 3/2, -y + 1/2, z + 1].
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Fap1: The molecular structure of the title compound with 30% probability displacement (arbitrary spheres for H atoms). One of the disordered imidazole components is omitted for clarify. Dashed lines indicate hydrogen bonding [symmetry codes: (i) -x + 3/2, -y + 3/2, z; (ii) -x + 3/2, -y + 1/2, z + 1].


Hexakis(1H-imidazole-κN)mangan-ese(II) triaqua-tris(1H-imidazole-κN)manganese(II) bis-(naphthalene-1,4-dicarboxyl-ate).

Li JH, Nie JJ, Xu DJ - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound with 30% probability displacement (arbitrary spheres for H atoms). One of the disordered imidazole components is omitted for clarify. Dashed lines indicate hydrogen bonding [symmetry codes: (i) -x + 3/2, -y + 3/2, z; (ii) -x + 3/2, -y + 1/2, z + 1].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961172&req=5

Fap1: The molecular structure of the title compound with 30% probability displacement (arbitrary spheres for H atoms). One of the disordered imidazole components is omitted for clarify. Dashed lines indicate hydrogen bonding [symmetry codes: (i) -x + 3/2, -y + 3/2, z; (ii) -x + 3/2, -y + 1/2, z + 1].
Bottom Line: In the crystal structure of the title compound, [Mn(C(3)H(4)N(2))(6)][Mn(C(3)H(4)N(2))(3)(H(2)O)(3)](C(12)H(6)O(4))(2), there are uncoordinated naphthalene-dicarboxyl-ate dianions and two kinds of Mn(II) complex cations, both assuming a distorted octa-hedral geometry.One Mn(II) cation is located on an inversion center and is coordinated by six imidazole mol-ecules, while the other Mn(II) cation is located on a twofold rotation axis and is coordinated by three water mol-ecules and three imidazole units.The naphthalene-dicarboxyl-ate dianions are linked to both Mn(II) complex cations via O-H⋯O and N-H⋯O hydrogen bonding, but no π-π stacking is observed between aromatic rings in the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Zhejiang University, People's Republic of China.

ABSTRACT
In the crystal structure of the title compound, [Mn(C(3)H(4)N(2))(6)][Mn(C(3)H(4)N(2))(3)(H(2)O)(3)](C(12)H(6)O(4))(2), there are uncoordinated naphthalene-dicarboxyl-ate dianions and two kinds of Mn(II) complex cations, both assuming a distorted octa-hedral geometry. One Mn(II) cation is located on an inversion center and is coordinated by six imidazole mol-ecules, while the other Mn(II) cation is located on a twofold rotation axis and is coordinated by three water mol-ecules and three imidazole units. The naphthalene-dicarboxyl-ate dianions are linked to both Mn(II) complex cations via O-H⋯O and N-H⋯O hydrogen bonding, but no π-π stacking is observed between aromatic rings in the crystal structure.

No MeSH data available.


Related in: MedlinePlus