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Poly[bis-(μ(2)-benzyl-oxyacetato-κO,O':O'')cadmium(II)].

Liu JW, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: Two benzyl-oxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyl-oxyacetate units in an octa-hedral geometry.The metal atom lies on a special position of 2 site symmetry.The phenyl group is disordered equally over two positions.

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ABSTRACT
The title cadmium derivative of benzyl-oxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a μ(2)-carboxyl-ate-bridged layer network. Two benzyl-oxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyl-oxyacetate units in an octa-hedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions.

No MeSH data available.


Thermal displacement ellipsoid plot (Barbour, 2001) illustrating the coordination geometry of Cd in [Cd(C9H9O3)2]n. Displacement ellipsoids are drawn at the 50% probability level and H atoms as spheres of arbitrary radii.
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Fap1: Thermal displacement ellipsoid plot (Barbour, 2001) illustrating the coordination geometry of Cd in [Cd(C9H9O3)2]n. Displacement ellipsoids are drawn at the 50% probability level and H atoms as spheres of arbitrary radii.


Poly[bis-(μ(2)-benzyl-oxyacetato-κO,O':O'')cadmium(II)].

Liu JW, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Thermal displacement ellipsoid plot (Barbour, 2001) illustrating the coordination geometry of Cd in [Cd(C9H9O3)2]n. Displacement ellipsoids are drawn at the 50% probability level and H atoms as spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961155&req=5

Fap1: Thermal displacement ellipsoid plot (Barbour, 2001) illustrating the coordination geometry of Cd in [Cd(C9H9O3)2]n. Displacement ellipsoids are drawn at the 50% probability level and H atoms as spheres of arbitrary radii.
Bottom Line: Two benzyl-oxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyl-oxyacetate units in an octa-hedral geometry.The metal atom lies on a special position of 2 site symmetry.The phenyl group is disordered equally over two positions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title cadmium derivative of benzyl-oxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a μ(2)-carboxyl-ate-bridged layer network. Two benzyl-oxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyl-oxyacetate units in an octa-hedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions.

No MeSH data available.