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{μ-6,6'-Dimeth-oxy-2,2'-[1,2-phenyl-ene-bis(nitrilo-methyl-idyne)]diphenolato}methano-lcopper(II)sodium(I).

Bian J - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The anion provides a planar cavity of four O atoms which accommodates a sodium cation.The crystal structure is stabilized by inter-molecular C-H⋯Cl and O-H⋯Cl hydrogen bonds, which link the mol-ecules into dimers.The crystal packing is further stabilized by weak π-π stacking inter-actions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: South China Sea Institute of Oceanology, Chinese Academy of Sciences, Guangzhou 510301, People's Republic of China, and Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101, People's Republic of China, and Graduate University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100049, People's Republic of China.

ABSTRACT
In the title complex, [NaCu(C(22)H(18)N(2)O(4))Cl(CH(3)OH)], the Cu atom lies nearly in the plane defined by the N(2)O(2) core of donor atoms, the out-of-plane distance being 0.001 (2) Å. The anion provides a planar cavity of four O atoms which accommodates a sodium cation. The coordination geometry around sodium is completed by the methanol O atom and a chloride ion. The four O atoms define a coordination plane containing the sodium cation [maximum displacement from the mean plane through the five atoms = 0.152 (3) Å for Na]. The crystal structure is stabilized by inter-molecular C-H⋯Cl and O-H⋯Cl hydrogen bonds, which link the mol-ecules into dimers. The crystal packing is further stabilized by weak π-π stacking inter-actions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) Å].

No MeSH data available.


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Packing diagram of structure of (I), view along the c axis. Hydrogen bonds are shown as dashed lines.
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Fap2: Packing diagram of structure of (I), view along the c axis. Hydrogen bonds are shown as dashed lines.


{μ-6,6'-Dimeth-oxy-2,2'-[1,2-phenyl-ene-bis(nitrilo-methyl-idyne)]diphenolato}methano-lcopper(II)sodium(I).

Bian J - Acta Crystallogr Sect E Struct Rep Online (2008)

Packing diagram of structure of (I), view along the c axis. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961150&req=5

Fap2: Packing diagram of structure of (I), view along the c axis. Hydrogen bonds are shown as dashed lines.
Bottom Line: The anion provides a planar cavity of four O atoms which accommodates a sodium cation.The crystal structure is stabilized by inter-molecular C-H⋯Cl and O-H⋯Cl hydrogen bonds, which link the mol-ecules into dimers.The crystal packing is further stabilized by weak π-π stacking inter-actions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: South China Sea Institute of Oceanology, Chinese Academy of Sciences, Guangzhou 510301, People's Republic of China, and Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101, People's Republic of China, and Graduate University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100049, People's Republic of China.

ABSTRACT
In the title complex, [NaCu(C(22)H(18)N(2)O(4))Cl(CH(3)OH)], the Cu atom lies nearly in the plane defined by the N(2)O(2) core of donor atoms, the out-of-plane distance being 0.001 (2) Å. The anion provides a planar cavity of four O atoms which accommodates a sodium cation. The coordination geometry around sodium is completed by the methanol O atom and a chloride ion. The four O atoms define a coordination plane containing the sodium cation [maximum displacement from the mean plane through the five atoms = 0.152 (3) Å for Na]. The crystal structure is stabilized by inter-molecular C-H⋯Cl and O-H⋯Cl hydrogen bonds, which link the mol-ecules into dimers. The crystal packing is further stabilized by weak π-π stacking inter-actions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) Å].

No MeSH data available.


Related in: MedlinePlus