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{μ-6,6'-Dimeth-oxy-2,2'-[1,2-phenyl-ene-bis(nitrilo-methyl-idyne)]diphenolato}methano-lcopper(II)sodium(I).

Bian J - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The anion provides a planar cavity of four O atoms which accommodates a sodium cation.The crystal structure is stabilized by inter-molecular C-H⋯Cl and O-H⋯Cl hydrogen bonds, which link the mol-ecules into dimers.The crystal packing is further stabilized by weak π-π stacking inter-actions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: South China Sea Institute of Oceanology, Chinese Academy of Sciences, Guangzhou 510301, People's Republic of China, and Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101, People's Republic of China, and Graduate University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100049, People's Republic of China.

ABSTRACT
In the title complex, [NaCu(C(22)H(18)N(2)O(4))Cl(CH(3)OH)], the Cu atom lies nearly in the plane defined by the N(2)O(2) core of donor atoms, the out-of-plane distance being 0.001 (2) Å. The anion provides a planar cavity of four O atoms which accommodates a sodium cation. The coordination geometry around sodium is completed by the methanol O atom and a chloride ion. The four O atoms define a coordination plane containing the sodium cation [maximum displacement from the mean plane through the five atoms = 0.152 (3) Å for Na]. The crystal structure is stabilized by inter-molecular C-H⋯Cl and O-H⋯Cl hydrogen bonds, which link the mol-ecules into dimers. The crystal packing is further stabilized by weak π-π stacking inter-actions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) Å].

No MeSH data available.


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View of the title compound (I), with displacement ellipsoids drawn at the 40% probability level.
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Fap1: View of the title compound (I), with displacement ellipsoids drawn at the 40% probability level.


{μ-6,6'-Dimeth-oxy-2,2'-[1,2-phenyl-ene-bis(nitrilo-methyl-idyne)]diphenolato}methano-lcopper(II)sodium(I).

Bian J - Acta Crystallogr Sect E Struct Rep Online (2008)

View of the title compound (I), with displacement ellipsoids drawn at the 40% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961150&req=5

Fap1: View of the title compound (I), with displacement ellipsoids drawn at the 40% probability level.
Bottom Line: The anion provides a planar cavity of four O atoms which accommodates a sodium cation.The crystal structure is stabilized by inter-molecular C-H⋯Cl and O-H⋯Cl hydrogen bonds, which link the mol-ecules into dimers.The crystal packing is further stabilized by weak π-π stacking inter-actions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: South China Sea Institute of Oceanology, Chinese Academy of Sciences, Guangzhou 510301, People's Republic of China, and Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101, People's Republic of China, and Graduate University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100049, People's Republic of China.

ABSTRACT
In the title complex, [NaCu(C(22)H(18)N(2)O(4))Cl(CH(3)OH)], the Cu atom lies nearly in the plane defined by the N(2)O(2) core of donor atoms, the out-of-plane distance being 0.001 (2) Å. The anion provides a planar cavity of four O atoms which accommodates a sodium cation. The coordination geometry around sodium is completed by the methanol O atom and a chloride ion. The four O atoms define a coordination plane containing the sodium cation [maximum displacement from the mean plane through the five atoms = 0.152 (3) Å for Na]. The crystal structure is stabilized by inter-molecular C-H⋯Cl and O-H⋯Cl hydrogen bonds, which link the mol-ecules into dimers. The crystal packing is further stabilized by weak π-π stacking inter-actions [centroid-centroid distances of 3.442 (4), 3.482 (3), 3.350 (2), 3.531 (4) 3.575 (2) and 3.604 (2) Å].

No MeSH data available.


Related in: MedlinePlus