Limits...
(3,5-Dichloro-salicylaldehyde thio-semi-carbazonato-κS,N,O)(N,N'-dimethyl-formamide-κO)copper(II) dimethyl-formamide solvate.

Wang Y, Liu Z, Gao JY - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro-salicylaldehyde thio-semi-carb-azonate ligand and one O atom from dimethyl-formamide.At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry.The crystal structure exhibits N-H⋯O and N-H⋯N hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Non-ferrous Metal Materials and New Processing Technology, Department of Materials and Chemical Engineering, Guilin University of Technology, Ministry of Education, Guilin 541004, People's Republic of China.

ABSTRACT
In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro-salicylaldehyde thio-semi-carb-azonate ligand and one O atom from dimethyl-formamide. At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry. The crystal structure exhibits N-H⋯O and N-H⋯N hydrogen bonds.

No MeSH data available.


The asymmetric unit showing 30% probability displacement ellipsoids. Carbon-bound H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2961129&req=5

Fap1: The asymmetric unit showing 30% probability displacement ellipsoids. Carbon-bound H atoms have been omitted for clarity.


(3,5-Dichloro-salicylaldehyde thio-semi-carbazonato-κS,N,O)(N,N'-dimethyl-formamide-κO)copper(II) dimethyl-formamide solvate.

Wang Y, Liu Z, Gao JY - Acta Crystallogr Sect E Struct Rep Online (2008)

The asymmetric unit showing 30% probability displacement ellipsoids. Carbon-bound H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961129&req=5

Fap1: The asymmetric unit showing 30% probability displacement ellipsoids. Carbon-bound H atoms have been omitted for clarity.
Bottom Line: In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro-salicylaldehyde thio-semi-carb-azonate ligand and one O atom from dimethyl-formamide.At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry.The crystal structure exhibits N-H⋯O and N-H⋯N hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Non-ferrous Metal Materials and New Processing Technology, Department of Materials and Chemical Engineering, Guilin University of Technology, Ministry of Education, Guilin 541004, People's Republic of China.

ABSTRACT
In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro-salicylaldehyde thio-semi-carb-azonate ligand and one O atom from dimethyl-formamide. At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry. The crystal structure exhibits N-H⋯O and N-H⋯N hydrogen bonds.

No MeSH data available.