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2-Fluoro-anilinium N-(2-fluoro-phenyl)oxamate.

Büyükgüngör O, Odabaşoğlu M - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The crystal structure of the title salt, C(6)H(7)FN(+)·C(8)H(5)FNO(3) (-), exhibits intra-molecular N-H⋯O and C-H⋯O and inter-molecular N-H⋯O and N-H⋯F hydrogen-bond inter-actions, the intra-molecular hydrogen-bond inter-actions generating S(6) and S(5) ring motifs.The dihedral angles between the aromatic ring and the intra-molecular hydrogen-bonded rings in the anion are 2.97 (7) and 6.70 (5)°.The two aromatic rings of the title compound are oriented with a dihedral angle of 77.25 (9)°.

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ABSTRACT
The crystal structure of the title salt, C(6)H(7)FN(+)·C(8)H(5)FNO(3) (-), exhibits intra-molecular N-H⋯O and C-H⋯O and inter-molecular N-H⋯O and N-H⋯F hydrogen-bond inter-actions, the intra-molecular hydrogen-bond inter-actions generating S(6) and S(5) ring motifs. The dihedral angles between the aromatic ring and the intra-molecular hydrogen-bonded rings in the anion are 2.97 (7) and 6.70 (5)°. The two aromatic rings of the title compound are oriented with a dihedral angle of 77.25 (9)°.

No MeSH data available.


A partial packing diagram of (I), showing the formation of R12(5)R42(8)R44(12) motifs. H atoms not involved in hydrogen bonds have been omitted for clarity. [Symmetry codes: (i) 1 - x, 1 - y, z; (ii) x, y - 1, z; (iii) -x, y, -z; (iv) 1 - x, -y, -z; (v) -x, -y, -z].
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Fap2: A partial packing diagram of (I), showing the formation of R12(5)R42(8)R44(12) motifs. H atoms not involved in hydrogen bonds have been omitted for clarity. [Symmetry codes: (i) 1 - x, 1 - y, z; (ii) x, y - 1, z; (iii) -x, y, -z; (iv) 1 - x, -y, -z; (v) -x, -y, -z].


2-Fluoro-anilinium N-(2-fluoro-phenyl)oxamate.

Büyükgüngör O, Odabaşoğlu M - Acta Crystallogr Sect E Struct Rep Online (2008)

A partial packing diagram of (I), showing the formation of R12(5)R42(8)R44(12) motifs. H atoms not involved in hydrogen bonds have been omitted for clarity. [Symmetry codes: (i) 1 - x, 1 - y, z; (ii) x, y - 1, z; (iii) -x, y, -z; (iv) 1 - x, -y, -z; (v) -x, -y, -z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961128&req=5

Fap2: A partial packing diagram of (I), showing the formation of R12(5)R42(8)R44(12) motifs. H atoms not involved in hydrogen bonds have been omitted for clarity. [Symmetry codes: (i) 1 - x, 1 - y, z; (ii) x, y - 1, z; (iii) -x, y, -z; (iv) 1 - x, -y, -z; (v) -x, -y, -z].
Bottom Line: The crystal structure of the title salt, C(6)H(7)FN(+)·C(8)H(5)FNO(3) (-), exhibits intra-molecular N-H⋯O and C-H⋯O and inter-molecular N-H⋯O and N-H⋯F hydrogen-bond inter-actions, the intra-molecular hydrogen-bond inter-actions generating S(6) and S(5) ring motifs.The dihedral angles between the aromatic ring and the intra-molecular hydrogen-bonded rings in the anion are 2.97 (7) and 6.70 (5)°.The two aromatic rings of the title compound are oriented with a dihedral angle of 77.25 (9)°.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The crystal structure of the title salt, C(6)H(7)FN(+)·C(8)H(5)FNO(3) (-), exhibits intra-molecular N-H⋯O and C-H⋯O and inter-molecular N-H⋯O and N-H⋯F hydrogen-bond inter-actions, the intra-molecular hydrogen-bond inter-actions generating S(6) and S(5) ring motifs. The dihedral angles between the aromatic ring and the intra-molecular hydrogen-bonded rings in the anion are 2.97 (7) and 6.70 (5)°. The two aromatic rings of the title compound are oriented with a dihedral angle of 77.25 (9)°.

No MeSH data available.