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Dicyclo-hexyl-ammonium bis-(chloro-difluoro-acetato-κO)cyclo-hexyl-diphenyl-stannate(IV).

Teo YY, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination.The four Sn-O distances are approximately equal in the two independent anions.Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter-actions giving rise to linear hydrogen-bonded chains.

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Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
In the title mixed-organyl stannate, (C(12)H(24)N)[Sn(C(6)H(5))(2)(C(6)H(11))(CClF(2)O(2))(2)], there are two cations and two anions in the asymmetric unit. Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The four Sn-O distances are approximately equal in the two independent anions. Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter-actions giving rise to linear hydrogen-bonded chains.

No MeSH data available.


Supramolecular chain formation in (I) with hydrogen bonding interactions shown as dotted lines.
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Fap2: Supramolecular chain formation in (I) with hydrogen bonding interactions shown as dotted lines.


Dicyclo-hexyl-ammonium bis-(chloro-difluoro-acetato-κO)cyclo-hexyl-diphenyl-stannate(IV).

Teo YY, Lo KM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Supramolecular chain formation in (I) with hydrogen bonding interactions shown as dotted lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961113&req=5

Fap2: Supramolecular chain formation in (I) with hydrogen bonding interactions shown as dotted lines.
Bottom Line: Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination.The four Sn-O distances are approximately equal in the two independent anions.Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter-actions giving rise to linear hydrogen-bonded chains.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

ABSTRACT
In the title mixed-organyl stannate, (C(12)H(24)N)[Sn(C(6)H(5))(2)(C(6)H(11))(CClF(2)O(2))(2)], there are two cations and two anions in the asymmetric unit. Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The four Sn-O distances are approximately equal in the two independent anions. Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter-actions giving rise to linear hydrogen-bonded chains.

No MeSH data available.