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catena-Poly[[[bis-[4-(1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthren-2-yl)phenol-κN,N]manganese(II)]-μ-naphthalene-1,4-dicarboxyl-ato-κO:O] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate].

Li HD, Li XY, Xu ML, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The 1,4-dicarboxyl-ate dianions in the title compound, [Mn(C(12)H(6)O(4))(C(19)H(12)N(4)O)(2)]·0.5C(12)H(8)O(4)·H(2)O, bond to two 4-(1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octa-hedral coordination geometry.The naphthalene-1,4-dicarboxylic acid solvent mol-ecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network.One NH group is disordered equally over two positions.

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ABSTRACT
The 1,4-dicarboxyl-ate dianions in the title compound, [Mn(C(12)H(6)O(4))(C(19)H(12)N(4)O)(2)]·0.5C(12)H(8)O(4)·H(2)O, bond to two 4-(1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octa-hedral coordination geometry. Adjacent chains inter-act with the uncoordinated water mol-ecules to form a three-dimensional network. The naphthalene-1,4-dicarboxylic acid solvent mol-ecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network. One NH group is disordered equally over two positions.

No MeSH data available.


Related in: MedlinePlus

Chain structure of the manganese-naphthalene-1,4-dicarboxylate network as illustrated by OLEX (Dolomanov et al., 2003).
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Fap2: Chain structure of the manganese-naphthalene-1,4-dicarboxylate network as illustrated by OLEX (Dolomanov et al., 2003).


catena-Poly[[[bis-[4-(1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthren-2-yl)phenol-κN,N]manganese(II)]-μ-naphthalene-1,4-dicarboxyl-ato-κO:O] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate].

Li HD, Li XY, Xu ML, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2008)

Chain structure of the manganese-naphthalene-1,4-dicarboxylate network as illustrated by OLEX (Dolomanov et al., 2003).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961106&req=5

Fap2: Chain structure of the manganese-naphthalene-1,4-dicarboxylate network as illustrated by OLEX (Dolomanov et al., 2003).
Bottom Line: The 1,4-dicarboxyl-ate dianions in the title compound, [Mn(C(12)H(6)O(4))(C(19)H(12)N(4)O)(2)]·0.5C(12)H(8)O(4)·H(2)O, bond to two 4-(1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octa-hedral coordination geometry.The naphthalene-1,4-dicarboxylic acid solvent mol-ecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network.One NH group is disordered equally over two positions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The 1,4-dicarboxyl-ate dianions in the title compound, [Mn(C(12)H(6)O(4))(C(19)H(12)N(4)O)(2)]·0.5C(12)H(8)O(4)·H(2)O, bond to two 4-(1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octa-hedral coordination geometry. Adjacent chains inter-act with the uncoordinated water mol-ecules to form a three-dimensional network. The naphthalene-1,4-dicarboxylic acid solvent mol-ecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network. One NH group is disordered equally over two positions.

No MeSH data available.


Related in: MedlinePlus