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Bis(2-bromo-pyridinium) hexa-chlorido-stannate(IV).

Ali BF, Al-Far R, Haddad SF - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion.Hydrogen-bonding inter-actions of two kinds, viz.These supra-molecular arrays are arranged in layers approximately parallel to (110) built up from anions inter-acting with six symmetry-related surrounding cations.

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ABSTRACT
The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion. The [SnCl(6)](2-) anion is located on an inversion center and forms a quasi-regular octa-hedral arrangement. Hydrogen-bonding inter-actions of two kinds, viz. N-H⋯Cl-Sn and C-H⋯Cl-Sn, along with Cl⋯Br inter-actions [3.4393 (15) Å], connect the ions in the crystal structure into two-dimensional supra-molecular arrays. These supra-molecular arrays are arranged in layers approximately parallel to (110) built up from anions inter-acting with six symmetry-related surrounding cations.

No MeSH data available.


Related in: MedlinePlus

A view of the asymmetric unit of (I), with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: A view of the asymmetric unit of (I), with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.


Bis(2-bromo-pyridinium) hexa-chlorido-stannate(IV).

Ali BF, Al-Far R, Haddad SF - Acta Crystallogr Sect E Struct Rep Online (2008)

A view of the asymmetric unit of (I), with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961104&req=5

Fap1: A view of the asymmetric unit of (I), with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion.Hydrogen-bonding inter-actions of two kinds, viz.These supra-molecular arrays are arranged in layers approximately parallel to (110) built up from anions inter-acting with six symmetry-related surrounding cations.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion. The [SnCl(6)](2-) anion is located on an inversion center and forms a quasi-regular octa-hedral arrangement. Hydrogen-bonding inter-actions of two kinds, viz. N-H⋯Cl-Sn and C-H⋯Cl-Sn, along with Cl⋯Br inter-actions [3.4393 (15) Å], connect the ions in the crystal structure into two-dimensional supra-molecular arrays. These supra-molecular arrays are arranged in layers approximately parallel to (110) built up from anions inter-acting with six symmetry-related surrounding cations.

No MeSH data available.


Related in: MedlinePlus