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Poly[diaqua-μ(2)-oxalato-di-μ(2)-pyrimidine-2-carboxyl-ato-dimanganese(II)].

Rodríguez-Diéguez A, Aouryaghal H, Mota AJ, Colacio E - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Mn(2)(C(2)O(4))(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)](n), the Mn(II) atom exhibits a distorted octa-hedral coordination geometry, with the centrosymmetric oxalate anion and the monoanionic pyrimidine-2-carboxyl-ate ligands generating a two-dimensional honeycomb network with a (6,3)-topology.

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ABSTRACT
In the title compound, [Mn(2)(C(2)O(4))(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)](n), the Mn(II) atom exhibits a distorted octa-hedral coordination geometry, with the centrosymmetric oxalate anion and the monoanionic pyrimidine-2-carboxyl-ate ligands generating a two-dimensional honeycomb network with a (6,3)-topology.

No MeSH data available.


The molecular structure of the asymmetric unit of [Mn2(pymca)2(ox)(H2O)2]n, showing the atom labels. Thermal ellipsoids are drawn at the 50% probability level. H atoms are represented as spheres of arbitrary radii.
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Fap1: The molecular structure of the asymmetric unit of [Mn2(pymca)2(ox)(H2O)2]n, showing the atom labels. Thermal ellipsoids are drawn at the 50% probability level. H atoms are represented as spheres of arbitrary radii.


Poly[diaqua-μ(2)-oxalato-di-μ(2)-pyrimidine-2-carboxyl-ato-dimanganese(II)].

Rodríguez-Diéguez A, Aouryaghal H, Mota AJ, Colacio E - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the asymmetric unit of [Mn2(pymca)2(ox)(H2O)2]n, showing the atom labels. Thermal ellipsoids are drawn at the 50% probability level. H atoms are represented as spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961100&req=5

Fap1: The molecular structure of the asymmetric unit of [Mn2(pymca)2(ox)(H2O)2]n, showing the atom labels. Thermal ellipsoids are drawn at the 50% probability level. H atoms are represented as spheres of arbitrary radii.
Bottom Line: In the title compound, [Mn(2)(C(2)O(4))(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)](n), the Mn(II) atom exhibits a distorted octa-hedral coordination geometry, with the centrosymmetric oxalate anion and the monoanionic pyrimidine-2-carboxyl-ate ligands generating a two-dimensional honeycomb network with a (6,3)-topology.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Mn(2)(C(2)O(4))(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)](n), the Mn(II) atom exhibits a distorted octa-hedral coordination geometry, with the centrosymmetric oxalate anion and the monoanionic pyrimidine-2-carboxyl-ate ligands generating a two-dimensional honeycomb network with a (6,3)-topology.

No MeSH data available.