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Bis(chloro-acetato)-κO,O';κO-methanol-κO-bis-(2-methyl-furo[3,2-c]pyridine-κN)copper(II).

Mikloš D, Miklovič J, Mrázová V, Moncol J, Segľa P - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: There is an intra-molecular O-H⋯O hydrogen bond.Inter-molecular C-H⋯O hydrogen bonds result in the formation of a three-dimensional network and π-π stacking inter-actions [3.44-3.83 Å] are observed between symmetry-related rings of 2-methyl-furo[3,2-c]pyridine.Further inter-actions in the crystal structure are a short Cl⋯Cl inter-action [3.384 (2)Å] and C-H⋯π inter-actions between 2-methyl-furo[3,2-c]pyridine rings.

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ABSTRACT
In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxyl-ate O atoms of two chloro-acetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methyl-furo[3,2-c]pyridine and one methanol O atom. There is an intra-molecular O-H⋯O hydrogen bond. Inter-molecular C-H⋯O hydrogen bonds result in the formation of a three-dimensional network and π-π stacking inter-actions [3.44-3.83 Å] are observed between symmetry-related rings of 2-methyl-furo[3,2-c]pyridine. Further inter-actions in the crystal structure are a short Cl⋯Cl inter-action [3.384 (2)Å] and C-H⋯π inter-actions between 2-methyl-furo[3,2-c]pyridine rings.

No MeSH data available.


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The crystal packing of the title compound with C–H···O hydrogen bonds, Cl···Cl contacts and π-π stacking interactions. Symmetry codes: (ii) -x + 3/2, y - 1/2, -z + 1/2; (iii) -x + 1, y, -z + 1/2; (v) -x + 3/2, y + 1/2, -z + 1/2; (vi) -x + 2, y, -z + 1/2].
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Fap2: The crystal packing of the title compound with C–H···O hydrogen bonds, Cl···Cl contacts and π-π stacking interactions. Symmetry codes: (ii) -x + 3/2, y - 1/2, -z + 1/2; (iii) -x + 1, y, -z + 1/2; (v) -x + 3/2, y + 1/2, -z + 1/2; (vi) -x + 2, y, -z + 1/2].


Bis(chloro-acetato)-κO,O';κO-methanol-κO-bis-(2-methyl-furo[3,2-c]pyridine-κN)copper(II).

Mikloš D, Miklovič J, Mrázová V, Moncol J, Segľa P - Acta Crystallogr Sect E Struct Rep Online (2008)

The crystal packing of the title compound with C–H···O hydrogen bonds, Cl···Cl contacts and π-π stacking interactions. Symmetry codes: (ii) -x + 3/2, y - 1/2, -z + 1/2; (iii) -x + 1, y, -z + 1/2; (v) -x + 3/2, y + 1/2, -z + 1/2; (vi) -x + 2, y, -z + 1/2].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961079&req=5

Fap2: The crystal packing of the title compound with C–H···O hydrogen bonds, Cl···Cl contacts and π-π stacking interactions. Symmetry codes: (ii) -x + 3/2, y - 1/2, -z + 1/2; (iii) -x + 1, y, -z + 1/2; (v) -x + 3/2, y + 1/2, -z + 1/2; (vi) -x + 2, y, -z + 1/2].
Bottom Line: There is an intra-molecular O-H⋯O hydrogen bond.Inter-molecular C-H⋯O hydrogen bonds result in the formation of a three-dimensional network and π-π stacking inter-actions [3.44-3.83 Å] are observed between symmetry-related rings of 2-methyl-furo[3,2-c]pyridine.Further inter-actions in the crystal structure are a short Cl⋯Cl inter-action [3.384 (2)Å] and C-H⋯π inter-actions between 2-methyl-furo[3,2-c]pyridine rings.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxyl-ate O atoms of two chloro-acetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methyl-furo[3,2-c]pyridine and one methanol O atom. There is an intra-molecular O-H⋯O hydrogen bond. Inter-molecular C-H⋯O hydrogen bonds result in the formation of a three-dimensional network and π-π stacking inter-actions [3.44-3.83 Å] are observed between symmetry-related rings of 2-methyl-furo[3,2-c]pyridine. Further inter-actions in the crystal structure are a short Cl⋯Cl inter-action [3.384 (2)Å] and C-H⋯π inter-actions between 2-methyl-furo[3,2-c]pyridine rings.

No MeSH data available.


Related in: MedlinePlus