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Hydroxonium triaqua-bis(biuret-κO,O')dichloridolanthanum(III) dichloride dihydrate.

Harrison WT - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O'-bidentate biuret mol-ecules and three water mol-ecules) and two chloride ions in an irregular arrangement.A network of N-H⋯O, N-H⋯Cl, O-H⋯O and O-H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network.The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.

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Affiliation: Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland.

ABSTRACT
In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O'-bidentate biuret mol-ecules and three water mol-ecules) and two chloride ions in an irregular arrangement. A network of N-H⋯O, N-H⋯Cl, O-H⋯O and O-H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.

No MeSH data available.


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Fragment of the packing for (I) displaying the hydrogen bonds (shows an double dashed lines) leading to chains arising from the complex cation, the hydroxonium ion and the uncoordinated water molecule. Symmetry code: (i) 1/2 - x, 1/2 + y, z.
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Fap2: Fragment of the packing for (I) displaying the hydrogen bonds (shows an double dashed lines) leading to chains arising from the complex cation, the hydroxonium ion and the uncoordinated water molecule. Symmetry code: (i) 1/2 - x, 1/2 + y, z.


Hydroxonium triaqua-bis(biuret-κO,O')dichloridolanthanum(III) dichloride dihydrate.

Harrison WT - Acta Crystallogr Sect E Struct Rep Online (2008)

Fragment of the packing for (I) displaying the hydrogen bonds (shows an double dashed lines) leading to chains arising from the complex cation, the hydroxonium ion and the uncoordinated water molecule. Symmetry code: (i) 1/2 - x, 1/2 + y, z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961074&req=5

Fap2: Fragment of the packing for (I) displaying the hydrogen bonds (shows an double dashed lines) leading to chains arising from the complex cation, the hydroxonium ion and the uncoordinated water molecule. Symmetry code: (i) 1/2 - x, 1/2 + y, z.
Bottom Line: In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O'-bidentate biuret mol-ecules and three water mol-ecules) and two chloride ions in an irregular arrangement.A network of N-H⋯O, N-H⋯Cl, O-H⋯O and O-H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network.The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland.

ABSTRACT
In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O'-bidentate biuret mol-ecules and three water mol-ecules) and two chloride ions in an irregular arrangement. A network of N-H⋯O, N-H⋯Cl, O-H⋯O and O-H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.

No MeSH data available.


Related in: MedlinePlus