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2,4,6-Triamino-1,3,5-triazine-1,3-diium aqua-penta-fluoridoaluminate.

Cadiau A, Hemon-Ribaud A, Leblanc M, Maisonneuve V - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, (C(3)H(8)N(6))[AlF(5)(H(2)O)], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,3,5-triazine-2,4,6-triamine (melamine), aqueous HF and water at 323 K for 48 h.The structure consists of [AlF(5)(H(2)O)](2-) octa-hedra and diprotonated melaminium cations.Cohesion is ensured by a three-dimensional network of hydrogen bonds.

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Affiliation: Laboratoire des Oxydes et Fluorures - UMR 6010 CNRS, Faculté des Sciences et Techniques, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France.

ABSTRACT
The title compound, (C(3)H(8)N(6))[AlF(5)(H(2)O)], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,3,5-triazine-2,4,6-triamine (melamine), aqueous HF and water at 323 K for 48 h. The structure consists of [AlF(5)(H(2)O)](2-) octa-hedra and diprotonated melaminium cations. Cohesion is ensured by a three-dimensional network of hydrogen bonds.

No MeSH data available.


Network of hydrogen bonds between melaminium cations and [AlF5(H2O)] octahedra. [Symmetry codes: (iii) 1 - x, y - 1/2, 1/2 - z; (iv) 1 - x, 1/2 + y, 1/2 - z; (v) 1 - x, -y, -z; (vi) 1 + x, 1/2 - y, z - 1/2]
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Fap3: Network of hydrogen bonds between melaminium cations and [AlF5(H2O)] octahedra. [Symmetry codes: (iii) 1 - x, y - 1/2, 1/2 - z; (iv) 1 - x, 1/2 + y, 1/2 - z; (v) 1 - x, -y, -z; (vi) 1 + x, 1/2 - y, z - 1/2]


2,4,6-Triamino-1,3,5-triazine-1,3-diium aqua-penta-fluoridoaluminate.

Cadiau A, Hemon-Ribaud A, Leblanc M, Maisonneuve V - Acta Crystallogr Sect E Struct Rep Online (2008)

Network of hydrogen bonds between melaminium cations and [AlF5(H2O)] octahedra. [Symmetry codes: (iii) 1 - x, y - 1/2, 1/2 - z; (iv) 1 - x, 1/2 + y, 1/2 - z; (v) 1 - x, -y, -z; (vi) 1 + x, 1/2 - y, z - 1/2]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961066&req=5

Fap3: Network of hydrogen bonds between melaminium cations and [AlF5(H2O)] octahedra. [Symmetry codes: (iii) 1 - x, y - 1/2, 1/2 - z; (iv) 1 - x, 1/2 + y, 1/2 - z; (v) 1 - x, -y, -z; (vi) 1 + x, 1/2 - y, z - 1/2]
Bottom Line: The title compound, (C(3)H(8)N(6))[AlF(5)(H(2)O)], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,3,5-triazine-2,4,6-triamine (melamine), aqueous HF and water at 323 K for 48 h.The structure consists of [AlF(5)(H(2)O)](2-) octa-hedra and diprotonated melaminium cations.Cohesion is ensured by a three-dimensional network of hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire des Oxydes et Fluorures - UMR 6010 CNRS, Faculté des Sciences et Techniques, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France.

ABSTRACT
The title compound, (C(3)H(8)N(6))[AlF(5)(H(2)O)], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,3,5-triazine-2,4,6-triamine (melamine), aqueous HF and water at 323 K for 48 h. The structure consists of [AlF(5)(H(2)O)](2-) octa-hedra and diprotonated melaminium cations. Cohesion is ensured by a three-dimensional network of hydrogen bonds.

No MeSH data available.