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N'-(3-Thienylmethyl-ene)pyridine-2-carbohydrazide.

Cheng H, Djukic B, Harrington LE, Britten JF, Lemaire MT - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The mol-ecule is nearly planar.The structure is stabilized by a weak inter-molecular N-H⋯O hydrogen bond.The distance between centroids of adjacent thio-phene rings [3.67 (8) Å] suggests the presence of π-π inter-actions.

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ABSTRACT
The title compound, C(11)H(9)N(3)OS, was prepared to investigate the coordination chemistry of thio-phene-containing ligands as precursors to inter-esting metallopolymers. The mol-ecule is nearly planar. The angle between the thio-phene and pyridine rings is 8.63 (4)° and features the expected trans configuration about the imine bond. The structure is stabilized by a weak inter-molecular N-H⋯O hydrogen bond. The distance between centroids of adjacent thio-phene rings [3.67 (8) Å] suggests the presence of π-π inter-actions.

No MeSH data available.


The packing of the title compound viewed along the c axis. The intermolecular hydrogen bond (N2—H2···O1) and other close contacts (H4···N1 and H5···O1) are indicated as dotted lines.
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Fap2: The packing of the title compound viewed along the c axis. The intermolecular hydrogen bond (N2—H2···O1) and other close contacts (H4···N1 and H5···O1) are indicated as dotted lines.


N'-(3-Thienylmethyl-ene)pyridine-2-carbohydrazide.

Cheng H, Djukic B, Harrington LE, Britten JF, Lemaire MT - Acta Crystallogr Sect E Struct Rep Online (2008)

The packing of the title compound viewed along the c axis. The intermolecular hydrogen bond (N2—H2···O1) and other close contacts (H4···N1 and H5···O1) are indicated as dotted lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961063&req=5

Fap2: The packing of the title compound viewed along the c axis. The intermolecular hydrogen bond (N2—H2···O1) and other close contacts (H4···N1 and H5···O1) are indicated as dotted lines.
Bottom Line: The mol-ecule is nearly planar.The structure is stabilized by a weak inter-molecular N-H⋯O hydrogen bond.The distance between centroids of adjacent thio-phene rings [3.67 (8) Å] suggests the presence of π-π inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(11)H(9)N(3)OS, was prepared to investigate the coordination chemistry of thio-phene-containing ligands as precursors to inter-esting metallopolymers. The mol-ecule is nearly planar. The angle between the thio-phene and pyridine rings is 8.63 (4)° and features the expected trans configuration about the imine bond. The structure is stabilized by a weak inter-molecular N-H⋯O hydrogen bond. The distance between centroids of adjacent thio-phene rings [3.67 (8) Å] suggests the presence of π-π inter-actions.

No MeSH data available.