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Hexakis(1H-imidazole-κN)nickel(II) bis-(3-thienylacetate).

Song WD, Ji LL, Wang H - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octa-hedral coordination geometry, defined by six N atoms from the imidazole ligands.Inter-molecular N-H⋯O hydrogen-bonding inter-actions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture.The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5).

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Affiliation: College of Science, Guang Dong Ocean University, Zhanjiang 524088, People's Republic of China.

ABSTRACT
In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octa-hedral coordination geometry, defined by six N atoms from the imidazole ligands. Inter-molecular N-H⋯O hydrogen-bonding inter-actions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture. The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5).

No MeSH data available.


A packing view of the title compound. The intermolecluar hydrogen bonds are shown as dashed lines.
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Fap2: A packing view of the title compound. The intermolecluar hydrogen bonds are shown as dashed lines.


Hexakis(1H-imidazole-κN)nickel(II) bis-(3-thienylacetate).

Song WD, Ji LL, Wang H - Acta Crystallogr Sect E Struct Rep Online (2008)

A packing view of the title compound. The intermolecluar hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961043&req=5

Fap2: A packing view of the title compound. The intermolecluar hydrogen bonds are shown as dashed lines.
Bottom Line: In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octa-hedral coordination geometry, defined by six N atoms from the imidazole ligands.Inter-molecular N-H⋯O hydrogen-bonding inter-actions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture.The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5).

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Science, Guang Dong Ocean University, Zhanjiang 524088, People's Republic of China.

ABSTRACT
In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octa-hedral coordination geometry, defined by six N atoms from the imidazole ligands. Inter-molecular N-H⋯O hydrogen-bonding inter-actions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture. The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5).

No MeSH data available.